Rational design of hierarchically porous birnessite-type manganese dioxides nanosheets on different one-dimensional titania-based nanowires for high performance supercapacitors

Yu Xin Zhang; Min Kuang; Xiao Dong Hao; Yan Liu; Ming Huang; Xiao Long Guo; Jing Yan; Gen Quan Han; Jing Li

doi:10.1016/j.jpowsour.2014.07.114

Rational design of hierarchically porous birnessite-type manganese dioxides nanosheets on different one-dimensional titania-based nanowires for high performance supercapacitors

Yu Xin Zhang, Min Kuang, Xiao Dong Hao, Yan Liu, Ming Huang, Xiao Long Guo, Jing Yan, Gen Quan Han, Jing Li

Research output: Contribution to journal › Article › peer-review

67 Scopus citations

Abstract

A facile and large-scale strategy of mesoporous birnessite-type manganese dioxide (MnO2) nanosheets on one-dimension (1D) H2Ti 3O7 and anatase/TiO2 (B) nanowires (NWs) is developed for high performance supercapacitors. The morphological characteristics of MnO2 nanoflakes on H2Ti 3O7 and anatase/TiO2 (B) NWs could be rationally designed with various characteristics (e.g., the sheet thickness, surface area). Interestingly, the MnO2/TiO2 NWs exhibit a more optimized electrochemical performance with specific capacitance of 120 F g-1 at current density of 0.1 A g-1 (based on MnO 2 + TiO2) than MnO2/H2Ti 3O7 NWs. An asymmetric supercapacitor of MnO 2/TiO2//activated graphene (AG) yields a better energy density of 29.8 Wh kg-1 than MnO2/H2Ti 3O7//AG asymmetric supercapacitor, while maintaining desirable cycling stability. Indeed, the pseudocapacitive difference is related to the substrates, unique structure and surface area. Especially, the anatase/TiO2 (B) mixed-phase system can provide good electronic conductivity and high utilization of MnO2 nanosheets. © 2014 Elsevier B.V. All rights reserved.

Original language	English (US)
Pages (from-to)	675-683
Number of pages	9
Journal	Journal of Power Sources
Volume	270
DOIs	https://doi.org/10.1016/j.jpowsour.2014.07.114
State	Published - Dec 2014
Externally published	Yes

Bibliographical note

KAUST Repository Item: Exported on 2020-10-01
Acknowledgements: The authors gratefully acknowledge the financial supports provided by National Natural Science Foundation of China (Grant no. 51104194 and 21103127), Doctoral Fund of Ministry of Education of China (20110191120014), No. 43 Scientific Research Foundation for the Returned Overseas Chinese Scholars, National Key laboratory of Fundamental Science of Micro/Nano-device and System Technology (2013MS06, Chongqing University), State Education Ministry and Fundamental Research Funds for the Central Universities (Project no. 106112013CDJZR120017 and CDJZR13130035, Chongqing University, PR China). The authors acknowledge support on electrochemical characterization by Dr. Kexin Yao in King Abdullah University of Science and Technology, Saudi Arabia.
This publication acknowledges KAUST support, but has no KAUST affiliated authors.

Access to Document

10.1016/j.jpowsour.2014.07.114

Cite this

Zhang, Y. X., Kuang, M., Hao, X. D., Liu, Y., Huang, M., Guo, X. L., Yan, J., Han, G. Q., & Li, J. (2014). Rational design of hierarchically porous birnessite-type manganese dioxides nanosheets on different one-dimensional titania-based nanowires for high performance supercapacitors. Journal of Power Sources, 270, 675-683. https://doi.org/10.1016/j.jpowsour.2014.07.114

@article{027de1b71faf42d19726faa69442b6a7,

title = "Rational design of hierarchically porous birnessite-type manganese dioxides nanosheets on different one-dimensional titania-based nanowires for high performance supercapacitors",

abstract = "A facile and large-scale strategy of mesoporous birnessite-type manganese dioxide (MnO2) nanosheets on one-dimension (1D) H2Ti 3O7 and anatase/TiO2 (B) nanowires (NWs) is developed for high performance supercapacitors. The morphological characteristics of MnO2 nanoflakes on H2Ti 3O7 and anatase/TiO2 (B) NWs could be rationally designed with various characteristics (e.g., the sheet thickness, surface area). Interestingly, the MnO2/TiO2 NWs exhibit a more optimized electrochemical performance with specific capacitance of 120 F g-1 at current density of 0.1 A g-1 (based on MnO 2 + TiO2) than MnO2/H2Ti 3O7 NWs. An asymmetric supercapacitor of MnO 2/TiO2//activated graphene (AG) yields a better energy density of 29.8 Wh kg-1 than MnO2/H2Ti 3O7//AG asymmetric supercapacitor, while maintaining desirable cycling stability. Indeed, the pseudocapacitive difference is related to the substrates, unique structure and surface area. Especially, the anatase/TiO2 (B) mixed-phase system can provide good electronic conductivity and high utilization of MnO2 nanosheets. {\textcopyright} 2014 Elsevier B.V. All rights reserved.",

author = "Zhang, {Yu Xin} and Min Kuang and Hao, {Xiao Dong} and Yan Liu and Ming Huang and Guo, {Xiao Long} and Jing Yan and Han, {Gen Quan} and Jing Li",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: The authors gratefully acknowledge the financial supports provided by National Natural Science Foundation of China (Grant no. 51104194 and 21103127), Doctoral Fund of Ministry of Education of China (20110191120014), No. 43 Scientific Research Foundation for the Returned Overseas Chinese Scholars, National Key laboratory of Fundamental Science of Micro/Nano-device and System Technology (2013MS06, Chongqing University), State Education Ministry and Fundamental Research Funds for the Central Universities (Project no. 106112013CDJZR120017 and CDJZR13130035, Chongqing University, PR China). The authors acknowledge support on electrochemical characterization by Dr. Kexin Yao in King Abdullah University of Science and Technology, Saudi Arabia. This publication acknowledges KAUST support, but has no KAUST affiliated authors.",

year = "2014",

month = dec,

doi = "10.1016/j.jpowsour.2014.07.114",

language = "English (US)",

volume = "270",

pages = "675--683",

journal = "Journal of Power Sources",

issn = "0378-7753",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - Rational design of hierarchically porous birnessite-type manganese dioxides nanosheets on different one-dimensional titania-based nanowires for high performance supercapacitors

AU - Zhang, Yu Xin

AU - Kuang, Min

AU - Hao, Xiao Dong

AU - Liu, Yan

AU - Huang, Ming

AU - Guo, Xiao Long

AU - Yan, Jing

AU - Han, Gen Quan

AU - Li, Jing

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: The authors gratefully acknowledge the financial supports provided by National Natural Science Foundation of China (Grant no. 51104194 and 21103127), Doctoral Fund of Ministry of Education of China (20110191120014), No. 43 Scientific Research Foundation for the Returned Overseas Chinese Scholars, National Key laboratory of Fundamental Science of Micro/Nano-device and System Technology (2013MS06, Chongqing University), State Education Ministry and Fundamental Research Funds for the Central Universities (Project no. 106112013CDJZR120017 and CDJZR13130035, Chongqing University, PR China). The authors acknowledge support on electrochemical characterization by Dr. Kexin Yao in King Abdullah University of Science and Technology, Saudi Arabia. This publication acknowledges KAUST support, but has no KAUST affiliated authors.

PY - 2014/12

Y1 - 2014/12

N2 - A facile and large-scale strategy of mesoporous birnessite-type manganese dioxide (MnO2) nanosheets on one-dimension (1D) H2Ti 3O7 and anatase/TiO2 (B) nanowires (NWs) is developed for high performance supercapacitors. The morphological characteristics of MnO2 nanoflakes on H2Ti 3O7 and anatase/TiO2 (B) NWs could be rationally designed with various characteristics (e.g., the sheet thickness, surface area). Interestingly, the MnO2/TiO2 NWs exhibit a more optimized electrochemical performance with specific capacitance of 120 F g-1 at current density of 0.1 A g-1 (based on MnO 2 + TiO2) than MnO2/H2Ti 3O7 NWs. An asymmetric supercapacitor of MnO 2/TiO2//activated graphene (AG) yields a better energy density of 29.8 Wh kg-1 than MnO2/H2Ti 3O7//AG asymmetric supercapacitor, while maintaining desirable cycling stability. Indeed, the pseudocapacitive difference is related to the substrates, unique structure and surface area. Especially, the anatase/TiO2 (B) mixed-phase system can provide good electronic conductivity and high utilization of MnO2 nanosheets. © 2014 Elsevier B.V. All rights reserved.

AB - A facile and large-scale strategy of mesoporous birnessite-type manganese dioxide (MnO2) nanosheets on one-dimension (1D) H2Ti 3O7 and anatase/TiO2 (B) nanowires (NWs) is developed for high performance supercapacitors. The morphological characteristics of MnO2 nanoflakes on H2Ti 3O7 and anatase/TiO2 (B) NWs could be rationally designed with various characteristics (e.g., the sheet thickness, surface area). Interestingly, the MnO2/TiO2 NWs exhibit a more optimized electrochemical performance with specific capacitance of 120 F g-1 at current density of 0.1 A g-1 (based on MnO 2 + TiO2) than MnO2/H2Ti 3O7 NWs. An asymmetric supercapacitor of MnO 2/TiO2//activated graphene (AG) yields a better energy density of 29.8 Wh kg-1 than MnO2/H2Ti 3O7//AG asymmetric supercapacitor, while maintaining desirable cycling stability. Indeed, the pseudocapacitive difference is related to the substrates, unique structure and surface area. Especially, the anatase/TiO2 (B) mixed-phase system can provide good electronic conductivity and high utilization of MnO2 nanosheets. © 2014 Elsevier B.V. All rights reserved.

UR - http://hdl.handle.net/10754/599449

UR - https://linkinghub.elsevier.com/retrieve/pii/S0378775314011689

UR - http://www.scopus.com/inward/record.url?scp=84906716208&partnerID=8YFLogxK

U2 - 10.1016/j.jpowsour.2014.07.114

DO - 10.1016/j.jpowsour.2014.07.114

M3 - Article

SN - 0378-7753

VL - 270

SP - 675

EP - 683

JO - Journal of Power Sources

JF - Journal of Power Sources

ER -

Rational design of hierarchically porous birnessite-type manganese dioxides nanosheets on different one-dimensional titania-based nanowires for high performance supercapacitors

Abstract

Bibliographical note

Access to Document

Other files and links

Fingerprint

Cite this