TY - JOUR
T1 - Properties of chlorinated aluminas. V. Cis-2-butene isomerization over alumina and chlorinated aluminas
AU - Basset, Jean-Marie Maurice
AU - Figueras, F.
AU - Mathieu, M. V.
AU - Prettre, M.
PY - 1970/1/1
Y1 - 1970/1/1
N2 - Kinetics of cis-2-butene isomerization were studied on pure and chlorinated aluminas. The surface reaction is rate controlling and produces trans-2-butene and 1-butene by two parallel reactions. The variations of catalytic activity with chlorine content support the existence of different types of sites; at least three kinds of active sites are proposed: oxygen ions having electron donor properties, weakly basic sites, and strong Lewis centers.
AB - Kinetics of cis-2-butene isomerization were studied on pure and chlorinated aluminas. The surface reaction is rate controlling and produces trans-2-butene and 1-butene by two parallel reactions. The variations of catalytic activity with chlorine content support the existence of different types of sites; at least three kinds of active sites are proposed: oxygen ions having electron donor properties, weakly basic sites, and strong Lewis centers.
UR - http://www.scopus.com/inward/record.url?scp=0014724610&partnerID=8YFLogxK
U2 - 10.1016/0021-9517(70)90194-6
DO - 10.1016/0021-9517(70)90194-6
M3 - Article
AN - SCOPUS:0014724610
SN - 0021-9517
VL - 16
SP - 53
EP - 61
JO - Journal of Catalysis
JF - Journal of Catalysis
IS - 1
ER -