Preparation of fluorinated biaryls through direct palladium-catalyzed coupling of polyfluoroarenes with aryltrifluoroborates

Xin Fang; Yuanyuan Huang; Xiaoqing Chen; Xiaoxi Lin; Zhengshuai Bai; Kuo-Wei Huang; Yaofeng Yuan; Zhiqiang Weng

doi:10.1016/j.jfluchem.2013.03.017

Preparation of fluorinated biaryls through direct palladium-catalyzed coupling of polyfluoroarenes with aryltrifluoroborates

Xin Fang, Yuanyuan Huang, Xiaoqing Chen, Xiaoxi Lin, Zhengshuai Bai, Kuo-Wei Huang, Yaofeng Yuan, Zhiqiang Weng

Research output: Contribution to journal › Article › peer-review

20 Scopus citations

Abstract

The direct palladium-catalyzed coupling of polyfluoroarenes with aryltrifluoroborates gave the desired products of fluorinated biaryls in good to excellent yields. A diverse set of important functional groups including methoxy, aldehyde, ester, nitro and halide can be well tolerated in the protocol. © 2013 Elsevier B.V. All rights reserved.

Original language	English (US)
Pages (from-to)	50-57
Number of pages	8
Journal	Journal of Fluorine Chemistry
Volume	151
DOIs	https://doi.org/10.1016/j.jfluchem.2013.03.017
State	Published - Jul 2013

Bibliographical note

KAUST Repository Item: Exported on 2020-10-01
Acknowledgements: We acknowledge the financial support from National Natural Science Foundation of China (21072030) and Fuzhou University (022318) to Z.W. and King Abdullah University of Science and Technology to K.-W. H.

ASJC Scopus subject areas

Biochemistry
Organic Chemistry
Environmental Chemistry
Physical and Theoretical Chemistry
Inorganic Chemistry

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10.1016/j.jfluchem.2013.03.017

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title = "Preparation of fluorinated biaryls through direct palladium-catalyzed coupling of polyfluoroarenes with aryltrifluoroborates",

abstract = "The direct palladium-catalyzed coupling of polyfluoroarenes with aryltrifluoroborates gave the desired products of fluorinated biaryls in good to excellent yields. A diverse set of important functional groups including methoxy, aldehyde, ester, nitro and halide can be well tolerated in the protocol. {\textcopyright} 2013 Elsevier B.V. All rights reserved.",

author = "Xin Fang and Yuanyuan Huang and Xiaoqing Chen and Xiaoxi Lin and Zhengshuai Bai and Kuo-Wei Huang and Yaofeng Yuan and Zhiqiang Weng",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: We acknowledge the financial support from National Natural Science Foundation of China (21072030) and Fuzhou University (022318) to Z.W. and King Abdullah University of Science and Technology to K.-W. H.",

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month = jul,

doi = "10.1016/j.jfluchem.2013.03.017",

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T1 - Preparation of fluorinated biaryls through direct palladium-catalyzed coupling of polyfluoroarenes with aryltrifluoroborates

AU - Fang, Xin

AU - Huang, Yuanyuan

AU - Chen, Xiaoqing

AU - Lin, Xiaoxi

AU - Bai, Zhengshuai

AU - Huang, Kuo-Wei

AU - Yuan, Yaofeng

AU - Weng, Zhiqiang

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: We acknowledge the financial support from National Natural Science Foundation of China (21072030) and Fuzhou University (022318) to Z.W. and King Abdullah University of Science and Technology to K.-W. H.

PY - 2013/7

Y1 - 2013/7

N2 - The direct palladium-catalyzed coupling of polyfluoroarenes with aryltrifluoroborates gave the desired products of fluorinated biaryls in good to excellent yields. A diverse set of important functional groups including methoxy, aldehyde, ester, nitro and halide can be well tolerated in the protocol. © 2013 Elsevier B.V. All rights reserved.

AB - The direct palladium-catalyzed coupling of polyfluoroarenes with aryltrifluoroborates gave the desired products of fluorinated biaryls in good to excellent yields. A diverse set of important functional groups including methoxy, aldehyde, ester, nitro and halide can be well tolerated in the protocol. © 2013 Elsevier B.V. All rights reserved.

UR - http://hdl.handle.net/10754/562833

UR - https://linkinghub.elsevier.com/retrieve/pii/S0022113913001413

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U2 - 10.1016/j.jfluchem.2013.03.017

DO - 10.1016/j.jfluchem.2013.03.017

M3 - Article

SN - 0022-1139

VL - 151

SP - 50

EP - 57

JO - Journal of Fluorine Chemistry

JF - Journal of Fluorine Chemistry

ER -

Preparation of fluorinated biaryls through direct palladium-catalyzed coupling of polyfluoroarenes with aryltrifluoroborates

Abstract

Bibliographical note

ASJC Scopus subject areas

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