Preparation of an extremely dense BaCe0.8Sm0.2O3-δ thin membrane based on an in situ reaction

Lei Bi; Shangquan Zhang; Shumin Fang; Lei Zhang; Kui Xie; Changrong Xia; Wei Liu

doi:10.1016/j.elecom.2008.04.035

Preparation of an extremely dense BaCe_0.8Sm_0.2O_3-δ thin membrane based on an in situ reaction

Lei Bi, Shangquan Zhang, Shumin Fang, Lei Zhang, Kui Xie, Changrong Xia, Wei Liu^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

54 Scopus citations

Abstract

The thin membrane of BaCe_0.8Sm_0.2O_3-δ (BCS) with high quality was successfully fabricated on porous NiO-BCS anode substrate through a novel in situ reaction method. The key part of this method is to directly spray well-mixed suspension of BaCO₃, CeO₂ and Sm₂O₃ instead of pre-synthesized BCS ceramic powder on the anode substrate. After sintering at 1400 °C for 5 h, the extremely dense electrolyte membrane in the thickness of 10 μm is obtained. A single cell was assembled with La_0.7Sr_0.3FeO_3-σ as cathode and tested with humidified hydrogen as fuel at 650 °C. The open circuit voltage (OCV) and maximum power density respectively reach 1.04 V and 535 mW/cm². Interface resistance of cell under open circuit condition was also investigated.

Original language	English (US)
Pages (from-to)	1005-1007
Number of pages	3
Journal	Electrochemistry Communications
Volume	10
Issue number	7
DOIs	https://doi.org/10.1016/j.elecom.2008.04.035
State	Published - Jul 2008
Externally published	Yes

Bibliographical note

Funding Information:
This work is supported by the National Natural Science Foundation of China (Grant Nos. 50730002 and 20371045).

Keywords

Barium cerate
In situ reaction
Proton conductor
Suspension spray

ASJC Scopus subject areas

Electrochemistry

Access to Document

10.1016/j.elecom.2008.04.035

Cite this

@article{2f119af7f4a441bfa4c8ed2a75ab170d,

title = "Preparation of an extremely dense BaCe0.8Sm0.2O3-δ thin membrane based on an in situ reaction",

abstract = "The thin membrane of BaCe0.8Sm0.2O3-δ (BCS) with high quality was successfully fabricated on porous NiO-BCS anode substrate through a novel in situ reaction method. The key part of this method is to directly spray well-mixed suspension of BaCO3, CeO2 and Sm2O3 instead of pre-synthesized BCS ceramic powder on the anode substrate. After sintering at 1400 °C for 5 h, the extremely dense electrolyte membrane in the thickness of 10 μm is obtained. A single cell was assembled with La0.7Sr0.3FeO3-σ as cathode and tested with humidified hydrogen as fuel at 650 °C. The open circuit voltage (OCV) and maximum power density respectively reach 1.04 V and 535 mW/cm2. Interface resistance of cell under open circuit condition was also investigated.",

keywords = "Barium cerate, In situ reaction, Proton conductor, Suspension spray",

author = "Lei Bi and Shangquan Zhang and Shumin Fang and Lei Zhang and Kui Xie and Changrong Xia and Wei Liu",

note = "Funding Information: This work is supported by the National Natural Science Foundation of China (Grant Nos. 50730002 and 20371045).",

year = "2008",

month = jul,

doi = "10.1016/j.elecom.2008.04.035",

language = "English (US)",

volume = "10",

pages = "1005--1007",

journal = "Electrochemistry Communications",

issn = "1388-2481",

publisher = "Elsevier Inc.",

number = "7",

}

TY - JOUR

T1 - Preparation of an extremely dense BaCe0.8Sm0.2O3-δ thin membrane based on an in situ reaction

AU - Bi, Lei

AU - Zhang, Shangquan

AU - Fang, Shumin

AU - Zhang, Lei

AU - Xie, Kui

AU - Xia, Changrong

AU - Liu, Wei

N1 - Funding Information: This work is supported by the National Natural Science Foundation of China (Grant Nos. 50730002 and 20371045).

PY - 2008/7

Y1 - 2008/7

N2 - The thin membrane of BaCe0.8Sm0.2O3-δ (BCS) with high quality was successfully fabricated on porous NiO-BCS anode substrate through a novel in situ reaction method. The key part of this method is to directly spray well-mixed suspension of BaCO3, CeO2 and Sm2O3 instead of pre-synthesized BCS ceramic powder on the anode substrate. After sintering at 1400 °C for 5 h, the extremely dense electrolyte membrane in the thickness of 10 μm is obtained. A single cell was assembled with La0.7Sr0.3FeO3-σ as cathode and tested with humidified hydrogen as fuel at 650 °C. The open circuit voltage (OCV) and maximum power density respectively reach 1.04 V and 535 mW/cm2. Interface resistance of cell under open circuit condition was also investigated.

AB - The thin membrane of BaCe0.8Sm0.2O3-δ (BCS) with high quality was successfully fabricated on porous NiO-BCS anode substrate through a novel in situ reaction method. The key part of this method is to directly spray well-mixed suspension of BaCO3, CeO2 and Sm2O3 instead of pre-synthesized BCS ceramic powder on the anode substrate. After sintering at 1400 °C for 5 h, the extremely dense electrolyte membrane in the thickness of 10 μm is obtained. A single cell was assembled with La0.7Sr0.3FeO3-σ as cathode and tested with humidified hydrogen as fuel at 650 °C. The open circuit voltage (OCV) and maximum power density respectively reach 1.04 V and 535 mW/cm2. Interface resistance of cell under open circuit condition was also investigated.

KW - Barium cerate

KW - In situ reaction

KW - Proton conductor

KW - Suspension spray

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U2 - 10.1016/j.elecom.2008.04.035

DO - 10.1016/j.elecom.2008.04.035

M3 - Article

AN - SCOPUS:45649084939

SN - 1388-2481

VL - 10

SP - 1005

EP - 1007

JO - Electrochemistry Communications

JF - Electrochemistry Communications

IS - 7

ER -