Precursor Engineering for Ambient-Compatible Antisolvent-Free Fabrication of High-Efficiency CsPbI2Br Perovskite Solar Cells

Chenyang Duan, Jian Cui, Miaomiao Zhang, Yu Han, Shaomin Yang, Huan Zhao, Hongtao Bian, Jianxi Yao, Kui Zhao, Zhike Liu, Shengzhong Liu

Research output: Contribution to journalArticlepeer-review

96 Scopus citations

Abstract

High temperature stable inorganic CsPbX3 (X: I, Br, or mixed halides) perovskites with their bandgap tailored by tuning the halide composition offer promising opportunities in the design of ideal top cells for high-efficiency tandem solar cells. Unfortunately, the current high-efficiency CsPbX3 perovskite solar cells (PSCs) are prepared in vacuum, a moisture-free glovebox or other low-humidity conditions due to their poor moisture stability. Herein, a new precursor system (HCOOCs, HPbI3, and HPbBr3) is developed to replace the traditional precursors (CsI, PbI2, and PbBr2) commonly used for solar cells of this type. Both the experiments and calculations reveal that a new complex (HCOOH•Cs+) is generated in this precursor system. The new complex is not only stable against aging in humid air ambient at 91% relative humidity, but also effectively slows the perovskite crystallization, making it possible to eliminate the popular antisolvent used in the perovskite CsPbI2Br film deposition. The CsPbI2Br PSCs based on the new precursor system achieve a champion efficiency of 16.14%, the highest for inorganic PSCs prepared in ambient air conditions. Meanwhile, high air stability is demonstrated for an unencapsulated CsPbI2Br PSC with 92% of the original efficiency remaining after more than 800 h aging in ambient air.
Original languageEnglish (US)
JournalAdvanced Energy Materials
Volume10
Issue number22
DOIs
StatePublished - Jun 1 2020
Externally publishedYes

Bibliographical note

Generated from Scopus record by KAUST IRTS on 2023-09-21

ASJC Scopus subject areas

  • Renewable Energy, Sustainability and the Environment
  • Materials Science(all)

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