Post-synthetic modification of porphyrin-encapsulating metal-organic materials by cooperative addition of inorganic salts to enhance CO 2/CH 4 selectivity

Zhenjie Zhang; Wenyang Gao; Łukasz Wojtas; Shengqian Ma; Mohamed Eddaoudi; Michael J. Zaworotko

doi:10.1002/anie.201203594

Post-synthetic modification of porphyrin-encapsulating metal-organic materials by cooperative addition of inorganic salts to enhance CO 2/CH 4 selectivity

Zhenjie Zhang, Wenyang Gao, Łukasz Wojtas, Shengqian Ma, Mohamed Eddaoudi, Michael J. Zaworotko

Research output: Contribution to journal › Article › peer-review

104 Scopus citations

Abstract

Keeping MOM: Reaction of biphenyl-3,4',5-tricarboxylate and Cd(NO 3) 2 in the presence of meso-tetra(N-methyl-4-pyridyl) porphine tetratosylate afforded porph@MOM-11, a microporous metal-organic material (MOM) that encapsulates cationic porphyrins and solvent in alternating open channels. Porph@MOM-11 has cation and anion binding sites that facilitate cooperative addition of inorganic salts (such as M +Cl -) in a stoichiometric fashion. © 2012 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Original language	English (US)
Pages (from-to)	9330-9334
Number of pages	5
Journal	Angewandte Chemie International Edition
Volume	51
Issue number	37
DOIs	https://doi.org/10.1002/anie.201203594
State	Published - Aug 21 2012

Bibliographical note

KAUST Repository Item: Exported on 2020-10-01
Acknowledgements: This work is supported by King Abdullah University of Science and Technology (FIC/2010/06). The microcrystal diffraction of porph(Cl-)@MOM-11(Mn2+) was carried at the Advanced Photon Source on beamline 15ID-B at ChemMatCARS Sector 15 (NSF/CHE-0822838 and DE-AC02-06CH11357).

ASJC Scopus subject areas

Chemistry(all)
Catalysis

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10.1002/anie.201203594

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@article{07a70888d6c6463ca82351deb55c3582,

title = "Post-synthetic modification of porphyrin-encapsulating metal-organic materials by cooperative addition of inorganic salts to enhance CO 2/CH 4 selectivity",

abstract = "Keeping MOM: Reaction of biphenyl-3,4',5-tricarboxylate and Cd(NO 3) 2 in the presence of meso-tetra(N-methyl-4-pyridyl) porphine tetratosylate afforded porph@MOM-11, a microporous metal-organic material (MOM) that encapsulates cationic porphyrins and solvent in alternating open channels. Porph@MOM-11 has cation and anion binding sites that facilitate cooperative addition of inorganic salts (such as M +Cl -) in a stoichiometric fashion. {\textcopyright} 2012 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.",

author = "Zhenjie Zhang and Wenyang Gao and {\L}ukasz Wojtas and Shengqian Ma and Mohamed Eddaoudi and Zaworotko, {Michael J.}",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: This work is supported by King Abdullah University of Science and Technology (FIC/2010/06). The microcrystal diffraction of porph(Cl-)@MOM-11(Mn2+) was carried at the Advanced Photon Source on beamline 15ID-B at ChemMatCARS Sector 15 (NSF/CHE-0822838 and DE-AC02-06CH11357).",

year = "2012",

month = aug,

day = "21",

doi = "10.1002/anie.201203594",

language = "English (US)",

volume = "51",

pages = "9330--9334",

journal = "Angewandte Chemie International Edition",

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publisher = "John Wiley and Sons Ltd",

number = "37",

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TY - JOUR

T1 - Post-synthetic modification of porphyrin-encapsulating metal-organic materials by cooperative addition of inorganic salts to enhance CO 2/CH 4 selectivity

AU - Zhang, Zhenjie

AU - Gao, Wenyang

AU - Wojtas, Łukasz

AU - Ma, Shengqian

AU - Eddaoudi, Mohamed

AU - Zaworotko, Michael J.

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: This work is supported by King Abdullah University of Science and Technology (FIC/2010/06). The microcrystal diffraction of porph(Cl-)@MOM-11(Mn2+) was carried at the Advanced Photon Source on beamline 15ID-B at ChemMatCARS Sector 15 (NSF/CHE-0822838 and DE-AC02-06CH11357).

PY - 2012/8/21

Y1 - 2012/8/21

N2 - Keeping MOM: Reaction of biphenyl-3,4',5-tricarboxylate and Cd(NO 3) 2 in the presence of meso-tetra(N-methyl-4-pyridyl) porphine tetratosylate afforded porph@MOM-11, a microporous metal-organic material (MOM) that encapsulates cationic porphyrins and solvent in alternating open channels. Porph@MOM-11 has cation and anion binding sites that facilitate cooperative addition of inorganic salts (such as M +Cl -) in a stoichiometric fashion. © 2012 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

AB - Keeping MOM: Reaction of biphenyl-3,4',5-tricarboxylate and Cd(NO 3) 2 in the presence of meso-tetra(N-methyl-4-pyridyl) porphine tetratosylate afforded porph@MOM-11, a microporous metal-organic material (MOM) that encapsulates cationic porphyrins and solvent in alternating open channels. Porph@MOM-11 has cation and anion binding sites that facilitate cooperative addition of inorganic salts (such as M +Cl -) in a stoichiometric fashion. © 2012 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

UR - http://hdl.handle.net/10754/562279

UR - http://doi.wiley.com/10.1002/anie.201203594

UR - http://www.scopus.com/inward/record.url?scp=84865856859&partnerID=8YFLogxK

U2 - 10.1002/anie.201203594

DO - 10.1002/anie.201203594

M3 - Article

SN - 1433-7851

VL - 51

SP - 9330

EP - 9334

JO - Angewandte Chemie International Edition

JF - Angewandte Chemie International Edition

IS - 37

ER -

Post-synthetic modification of porphyrin-encapsulating metal-organic materials by cooperative addition of inorganic salts to enhance CO 2/CH 4 selectivity

Abstract

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CCDC 878570: Experimental Crystal Structure Determination : catena-(hemi-barium chloro-(4,4',4'',4'''-porphyrin-5,10,15,20-tetrayltetrakis(1-methylpyridinium))-cadmium tetrakis(mu~5~-biphenyl-3,4',5-tricarboxylato)-tetra-cadmium unknown solvate trihydrate)

CCDC 878573: Experimental Crystal Structure Determination : catena-(sodium chloro-(4,4',4'',4'''-porphyrin-5,10,15,20-tetrayltetrakis(1-methylpyridinium))-cadmium tetrakis(mu~5~-biphenyl-3,4',5-tricarboxylato)-tetra-cadmium unknown solvate trihydrate)

CCDC 878574: Experimental Crystal Structure Determination : catena-(aqua-(4,4',4'',4'''-porphyrin-5,10,15,20-tetrayltetrakis(1-methylpyridinium))-cadmium tetrakis(mu~5~-biphenyl-3,4',5-tricarboxylato)-tetra-cadmium unknown solvate)

Cite this

Post-synthetic modification of porphyrin-encapsulating metal-organic materials by cooperative addition of inorganic salts to enhance CO 2/CH 4 selectivity

Abstract

Bibliographical note

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Datasets

CCDC 878570: Experimental Crystal Structure Determination : catena-(hemi-barium chloro-(4,4',4'',4'''-porphyrin-5,10,15,20-tetrayltetrakis(1-methylpyridinium))-cadmium tetrakis(mu~5~-biphenyl-3,4',5-tricarboxylato)-tetra-cadmium unknown solvate trihydrate)

CCDC 878573: Experimental Crystal Structure Determination : catena-(sodium chloro-(4,4',4'',4'''-porphyrin-5,10,15,20-tetrayltetrakis(1-methylpyridinium))-cadmium tetrakis(mu~5~-biphenyl-3,4',5-tricarboxylato)-tetra-cadmium unknown solvate trihydrate)

CCDC 878574: Experimental Crystal Structure Determination : catena-(aqua-(4,4',4'',4'''-porphyrin-5,10,15,20-tetrayltetrakis(1-methylpyridinium))-cadmium tetrakis(mu~5~-biphenyl-3,4',5-tricarboxylato)-tetra-cadmium unknown solvate)

Cite this