Post-assembly transformations of porphyrin-containing metal-organic framework (MOF) films fabricated via automated layer-by-layer coordination

Monica So; M. Hassan Beyzavi; Rohan Sawhney; Osama Shekhah; Mohamed Eddaoudi; Salih Salem Al-Juaid; Joseph T. Hupp; Omar K. Farha

doi:10.1039/c4cc05727a

Post-assembly transformations of porphyrin-containing metal-organic framework (MOF) films fabricated via automated layer-by-layer coordination

Monica So, M. Hassan Beyzavi, Rohan Sawhney, Osama Shekhah, Mohamed Eddaoudi, Salih Salem Al-Juaid, Joseph T. Hupp, Omar K. Farha

Research output: Contribution to journal › Article › peer-review

52 Scopus citations

Abstract

Herein, we demonstrate the robustness of layer-by-layer (LbL)-assembled, pillared-paddlewheel-type MOF films toward conversion to new or modified MOFs via solvent-assisted linker exchange (SALE) and post-assembly linker metalation. Further, we show that LbL synthesis can afford MOFs that have proven inaccessible through other de novo strategies.

Original language	English (US)
Pages (from-to)	85-88
Number of pages	4
Journal	Chem. Commun.
Volume	51
Issue number	1
DOIs	https://doi.org/10.1039/c4cc05727a
State	Published - 2015

Bibliographical note

KAUST Repository Item: Exported on 2020-10-01
Acknowledgements: O.K.F and J.T.H gratefully acknowledge funding from the Army Research Office (project number W911NF-13-1-0229). M.C.S. acknowledges support from the National Defense Science & Engineering Graduate Fellowship Program. M. H. B. acknowledges support from the Institute for Sustainability and Energy at Northwestern University. The authors are grateful for the help of Dr Diego Gomez-Gualdron for simulation of single crystals of the MOFs and the use of experimental facilities at the Integrated Molecular Structure Education and Research Center and the Northwestern University Atomic- and Nanoscale Characterization Experimental Center (NUANCE, Keck-II).

ASJC Scopus subject areas

Materials Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Ceramics and Composites
General Chemistry
Catalysis
Electronic, Optical and Magnetic Materials

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10.1039/c4cc05727a

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title = "Post-assembly transformations of porphyrin-containing metal-organic framework (MOF) films fabricated via automated layer-by-layer coordination",

abstract = "Herein, we demonstrate the robustness of layer-by-layer (LbL)-assembled, pillared-paddlewheel-type MOF films toward conversion to new or modified MOFs via solvent-assisted linker exchange (SALE) and post-assembly linker metalation. Further, we show that LbL synthesis can afford MOFs that have proven inaccessible through other de novo strategies.",

author = "Monica So and Beyzavi, {M. Hassan} and Rohan Sawhney and Osama Shekhah and Mohamed Eddaoudi and Al-Juaid, {Salih Salem} and Hupp, {Joseph T.} and Farha, {Omar K.}",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: O.K.F and J.T.H gratefully acknowledge funding from the Army Research Office (project number W911NF-13-1-0229). M.C.S. acknowledges support from the National Defense Science & Engineering Graduate Fellowship Program. M. H. B. acknowledges support from the Institute for Sustainability and Energy at Northwestern University. The authors are grateful for the help of Dr Diego Gomez-Gualdron for simulation of single crystals of the MOFs and the use of experimental facilities at the Integrated Molecular Structure Education and Research Center and the Northwestern University Atomic- and Nanoscale Characterization Experimental Center (NUANCE, Keck-II).",

year = "2015",

doi = "10.1039/c4cc05727a",

language = "English (US)",

volume = "51",

pages = "85--88",

journal = "Chem. Commun.",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "1",

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T1 - Post-assembly transformations of porphyrin-containing metal-organic framework (MOF) films fabricated via automated layer-by-layer coordination

AU - So, Monica

AU - Beyzavi, M. Hassan

AU - Sawhney, Rohan

AU - Shekhah, Osama

AU - Eddaoudi, Mohamed

AU - Al-Juaid, Salih Salem

AU - Hupp, Joseph T.

AU - Farha, Omar K.

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: O.K.F and J.T.H gratefully acknowledge funding from the Army Research Office (project number W911NF-13-1-0229). M.C.S. acknowledges support from the National Defense Science & Engineering Graduate Fellowship Program. M. H. B. acknowledges support from the Institute for Sustainability and Energy at Northwestern University. The authors are grateful for the help of Dr Diego Gomez-Gualdron for simulation of single crystals of the MOFs and the use of experimental facilities at the Integrated Molecular Structure Education and Research Center and the Northwestern University Atomic- and Nanoscale Characterization Experimental Center (NUANCE, Keck-II).

PY - 2015

Y1 - 2015

N2 - Herein, we demonstrate the robustness of layer-by-layer (LbL)-assembled, pillared-paddlewheel-type MOF films toward conversion to new or modified MOFs via solvent-assisted linker exchange (SALE) and post-assembly linker metalation. Further, we show that LbL synthesis can afford MOFs that have proven inaccessible through other de novo strategies.

AB - Herein, we demonstrate the robustness of layer-by-layer (LbL)-assembled, pillared-paddlewheel-type MOF films toward conversion to new or modified MOFs via solvent-assisted linker exchange (SALE) and post-assembly linker metalation. Further, we show that LbL synthesis can afford MOFs that have proven inaccessible through other de novo strategies.

UR - http://hdl.handle.net/10754/563929

UR - http://xlink.rsc.org/?DOI=C4CC05727A

UR - http://www.scopus.com/inward/record.url?scp=84915750591&partnerID=8YFLogxK

U2 - 10.1039/c4cc05727a

DO - 10.1039/c4cc05727a

M3 - Article

SN - 1359-7345

VL - 51

SP - 85

EP - 88

JO - Chem. Commun.

JF - Chem. Commun.

IS - 1

ER -

Post-assembly transformations of porphyrin-containing metal-organic framework (MOF) films fabricated via automated layer-by-layer coordination

Abstract

Bibliographical note

ASJC Scopus subject areas

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