Porous homo- and heterochiral cobalt(II) aspartates with high thermal stability of the metal-organic framework

M. P. Yutkin; M. S. Zavakhina; D. G. Samsonenko; D. N. Dybtsev; V. P. Fedin

doi:10.1007/s11172-010-0154-8

Porous homo- and heterochiral cobalt(II) aspartates with high thermal stability of the metal-organic framework

M. P. Yutkin, M. S. Zavakhina, D. G. Samsonenko, D. N. Dybtsev, V. P. Fedin

Research output: Contribution to journal › Article › peer-review

19 Scopus citations

Abstract

Metal-organic coordination polymers with the compositions [Co ₂(L-asp) ₂-(bpy)] • MeOH • H₂O (1), [Co₂(L-asp)₂(bpe)] • 0.28(bpe) • H₂O (2), and [Co₂(d-asp)(l-asp)-(bpa)] • 0.25(bpa) • 1.5H ₂O (3) (H₂asp is aspartic acid, bpy is 4,4′-bipyridine, bpe is trans-bis(4- pyridyl)ethylene, and bpa is 1,2-bis(4-pyridyl)ethane) were synthesized on heating cobalt(II) as-partate and N-donor ligands (bpy, bpe, or bpa) in an aqueous-methanol mixture. The structures of compounds 1- ash;3 were established by X-ray diffraction analysis and confirmed by X-ray powder crystallography, IR spectroscopy, thermogravimetry, and elemental analysis. The stability of the synthesized coordination polymers was studied. It was shown that they retain the framework structure on heating to 300 °C.

Original language	English (US)
Pages (from-to)	733-740
Number of pages	8
Journal	Russian Chemical Bulletin
Volume	59
Issue number	4
DOIs	https://doi.org/10.1007/s11172-010-0154-8
State	Published - Apr 2010
Externally published	Yes

Keywords

X-ray diffraction analysis
X-ray powder diffraction
amino acids
aspartic acid
chiral complexes
cobalt(II) complexes
coordination polymers
framework structures

ASJC Scopus subject areas

General Chemistry

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10.1007/s11172-010-0154-8

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title = "Porous homo- and heterochiral cobalt(II) aspartates with high thermal stability of the metal-organic framework",

abstract = "Metal-organic coordination polymers with the compositions [Co 2(L-asp) 2-(bpy)] • MeOH • H2O (1), [Co2(L-asp)2(bpe)] • 0.28(bpe) • H2O (2), and [Co2(d-asp)(l-asp)-(bpa)] • 0.25(bpa) • 1.5H 2O (3) (H2asp is aspartic acid, bpy is 4,4′-bipyridine, bpe is trans-bis(4- pyridyl)ethylene, and bpa is 1,2-bis(4-pyridyl)ethane) were synthesized on heating cobalt(II) as-partate and N-donor ligands (bpy, bpe, or bpa) in an aqueous-methanol mixture. The structures of compounds 1- ash;3 were established by X-ray diffraction analysis and confirmed by X-ray powder crystallography, IR spectroscopy, thermogravimetry, and elemental analysis. The stability of the synthesized coordination polymers was studied. It was shown that they retain the framework structure on heating to 300 °C.",

keywords = "X-ray diffraction analysis, X-ray powder diffraction, amino acids, aspartic acid, chiral complexes, cobalt(II) complexes, coordination polymers, framework structures",

author = "Yutkin, {M. P.} and Zavakhina, {M. S.} and Samsonenko, {D. G.} and Dybtsev, {D. N.} and Fedin, {V. P.}",

year = "2010",

month = apr,

doi = "10.1007/s11172-010-0154-8",

language = "English (US)",

volume = "59",

pages = "733--740",

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T1 - Porous homo- and heterochiral cobalt(II) aspartates with high thermal stability of the metal-organic framework

AU - Yutkin, M. P.

AU - Zavakhina, M. S.

AU - Samsonenko, D. G.

AU - Dybtsev, D. N.

AU - Fedin, V. P.

PY - 2010/4

Y1 - 2010/4

N2 - Metal-organic coordination polymers with the compositions [Co 2(L-asp) 2-(bpy)] • MeOH • H2O (1), [Co2(L-asp)2(bpe)] • 0.28(bpe) • H2O (2), and [Co2(d-asp)(l-asp)-(bpa)] • 0.25(bpa) • 1.5H 2O (3) (H2asp is aspartic acid, bpy is 4,4′-bipyridine, bpe is trans-bis(4- pyridyl)ethylene, and bpa is 1,2-bis(4-pyridyl)ethane) were synthesized on heating cobalt(II) as-partate and N-donor ligands (bpy, bpe, or bpa) in an aqueous-methanol mixture. The structures of compounds 1- ash;3 were established by X-ray diffraction analysis and confirmed by X-ray powder crystallography, IR spectroscopy, thermogravimetry, and elemental analysis. The stability of the synthesized coordination polymers was studied. It was shown that they retain the framework structure on heating to 300 °C.

AB - Metal-organic coordination polymers with the compositions [Co 2(L-asp) 2-(bpy)] • MeOH • H2O (1), [Co2(L-asp)2(bpe)] • 0.28(bpe) • H2O (2), and [Co2(d-asp)(l-asp)-(bpa)] • 0.25(bpa) • 1.5H 2O (3) (H2asp is aspartic acid, bpy is 4,4′-bipyridine, bpe is trans-bis(4- pyridyl)ethylene, and bpa is 1,2-bis(4-pyridyl)ethane) were synthesized on heating cobalt(II) as-partate and N-donor ligands (bpy, bpe, or bpa) in an aqueous-methanol mixture. The structures of compounds 1- ash;3 were established by X-ray diffraction analysis and confirmed by X-ray powder crystallography, IR spectroscopy, thermogravimetry, and elemental analysis. The stability of the synthesized coordination polymers was studied. It was shown that they retain the framework structure on heating to 300 °C.

KW - X-ray diffraction analysis

KW - X-ray powder diffraction

KW - amino acids

KW - aspartic acid

KW - chiral complexes

KW - cobalt(II) complexes

KW - coordination polymers

KW - framework structures

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DO - 10.1007/s11172-010-0154-8

M3 - Article

AN - SCOPUS:77958582023

SN - 1066-5285

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JF - Russian Chemical Bulletin

IS - 4

ER -

Porous homo- and heterochiral cobalt(II) aspartates with high thermal stability of the metal-organic framework

Abstract

Keywords

ASJC Scopus subject areas

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