Abstract
An efficient synthetic route to pure, high molecular weight poly(p-hydroxystyrene) is reported. The route involves synthesis of a new monomer, p-tert-butoxycarbonyloxystyrene, polymerization by radical initiation or by cationic initiation in liquid SO2, followed by thermolysis or acidolysis of the tert-butoxycarbonyl protecting group. Porous, crosslinked resin beads containing the nucleophilic, phenol pendant group have been prepared in a similar fashion from the precursor terpolymer of p-tert-butoxycarbonyloxystyrene, styrene and divinylbenzene. The utility of this resin for solid-phase synthesis has been demonstrated.
Original language | English (US) |
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Pages (from-to) | 995-1000 |
Number of pages | 6 |
Journal | Polymer |
Volume | 24 |
Issue number | 8 |
DOIs | |
State | Published - Aug 1983 |
Externally published | Yes |
Keywords
- Poly(p-tert-butoxycarbonyloxystyrene)
- p-tert-butoxycarbonyloxybenzaldehyde
- p-tert-butoxycarbonyloxystyrene
- poly(p-hydroxystyrene)
- poly(vinyl phenol)
- polymerization
ASJC Scopus subject areas
- Organic Chemistry
- Polymers and Plastics
- Materials Chemistry