Polymers of intrinsic microporosity derived from bis(phenazyl) monomers

Bader S. Ghanem; Neil B. McKeown; Peter M. Budd; Detlev Fritsch

doi:10.1021/ma071846r

Polymers of intrinsic microporosity derived from bis(phenazyl) monomers

Bader S. Ghanem, Neil B. McKeown, Peter M. Budd, Detlev Fritsch

Research output: Contribution to journal › Article › peer-review

147 Scopus citations

Abstract

Novel polymers of intrinsic microporosity (PIMs) are prepared from bis(phenazyl) monomers derived from readily available bis(catechol)s. One of the polymers (termed PIM-7) has an excellent combination of properties with high internal surface area, good film-forming characteristics, and gas transport properties that make it a suitable candidate for gas separation membranes. The high gas permeability and good ideal selectivity of PIM-7 place it above Robeson's upper-bound for a number of commercially important gas pairs (e.g., O₂/N₂, CO₂/CH₄, and CO ₂/N₂).

Original language	English (US)
Pages (from-to)	1640-1646
Number of pages	7
Journal	Macromolecules
Volume	41
Issue number	5
DOIs	https://doi.org/10.1021/ma071846r
State	Published - Mar 11 2008
Externally published	Yes

ASJC Scopus subject areas

Organic Chemistry
Polymers and Plastics
Inorganic Chemistry
Materials Chemistry

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10.1021/ma071846r

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title = "Polymers of intrinsic microporosity derived from bis(phenazyl) monomers",

abstract = "Novel polymers of intrinsic microporosity (PIMs) are prepared from bis(phenazyl) monomers derived from readily available bis(catechol)s. One of the polymers (termed PIM-7) has an excellent combination of properties with high internal surface area, good film-forming characteristics, and gas transport properties that make it a suitable candidate for gas separation membranes. The high gas permeability and good ideal selectivity of PIM-7 place it above Robeson's upper-bound for a number of commercially important gas pairs (e.g., O2/N2, CO2/CH4, and CO 2/N2).",

author = "Ghanem, {Bader S.} and McKeown, {Neil B.} and Budd, {Peter M.} and Detlev Fritsch",

year = "2008",

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AU - Ghanem, Bader S.

AU - McKeown, Neil B.

AU - Budd, Peter M.

AU - Fritsch, Detlev

PY - 2008/3/11

Y1 - 2008/3/11

N2 - Novel polymers of intrinsic microporosity (PIMs) are prepared from bis(phenazyl) monomers derived from readily available bis(catechol)s. One of the polymers (termed PIM-7) has an excellent combination of properties with high internal surface area, good film-forming characteristics, and gas transport properties that make it a suitable candidate for gas separation membranes. The high gas permeability and good ideal selectivity of PIM-7 place it above Robeson's upper-bound for a number of commercially important gas pairs (e.g., O2/N2, CO2/CH4, and CO 2/N2).

AB - Novel polymers of intrinsic microporosity (PIMs) are prepared from bis(phenazyl) monomers derived from readily available bis(catechol)s. One of the polymers (termed PIM-7) has an excellent combination of properties with high internal surface area, good film-forming characteristics, and gas transport properties that make it a suitable candidate for gas separation membranes. The high gas permeability and good ideal selectivity of PIM-7 place it above Robeson's upper-bound for a number of commercially important gas pairs (e.g., O2/N2, CO2/CH4, and CO 2/N2).

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U2 - 10.1021/ma071846r

DO - 10.1021/ma071846r

M3 - Article

AN - SCOPUS:41849101076

SN - 0024-9297

VL - 41

SP - 1640

EP - 1646

JO - Macromolecules

JF - Macromolecules

IS - 5

ER -

Polymers of intrinsic microporosity derived from bis(phenazyl) monomers

Abstract

ASJC Scopus subject areas

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