Polymeric organometallic architectures of novel P-Se anions

Weifeng Shi; Maryam Shafaei-Fallah; Le Zhang; Christopher E. Anson; Eberhard Matern; Alexander Rothenberger

doi:10.1002/chem.200600626

Polymeric organometallic architectures of novel P-Se anions

Weifeng Shi, Maryam Shafaei-Fallah, Le Zhang, Christopher E. Anson, Eberhard Matern, Alexander Rothenberger^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

33 Scopus citations

Abstract

The characterisation of a series of compounds obtained from Woollins' reagent (W.R.) offers a novel approach to organometallic coordination polymers. The syntheses were achieved by nucleophilic ring-opening reactions of W.R. with metal salts and crystallisation using solvent-diffusion techniques. One-dimensional coordination polymers are formed as a result, and we demonstrate that the dimensionality of the polymers can be influenced by using hydrated metal salts or by the construction of heterometallic arrangements.

Original language	English (US)
Pages (from-to)	598-603
Number of pages	6
Journal	Chemistry - A European Journal
Volume	13
Issue number	2
DOIs	https://doi.org/10.1002/chem.200600626
State	Published - 2007
Externally published	Yes

Keywords

Alkali metals
Phosphorus
Polymers
Selenium
Supramolecular chemistry

ASJC Scopus subject areas

Catalysis
Organic Chemistry

Access to Document

10.1002/chem.200600626

Cite this

@article{5eb41057b402464c818aea70917c8058,

title = "Polymeric organometallic architectures of novel P-Se anions",

abstract = "The characterisation of a series of compounds obtained from Woollins' reagent (W.R.) offers a novel approach to organometallic coordination polymers. The syntheses were achieved by nucleophilic ring-opening reactions of W.R. with metal salts and crystallisation using solvent-diffusion techniques. One-dimensional coordination polymers are formed as a result, and we demonstrate that the dimensionality of the polymers can be influenced by using hydrated metal salts or by the construction of heterometallic arrangements.",

keywords = "Alkali metals, Phosphorus, Polymers, Selenium, Supramolecular chemistry",

author = "Weifeng Shi and Maryam Shafaei-Fallah and Le Zhang and Anson, {Christopher E.} and Eberhard Matern and Alexander Rothenberger",

year = "2007",

doi = "10.1002/chem.200600626",

language = "English (US)",

volume = "13",

pages = "598--603",

journal = "Chemistry - A European Journal",

issn = "0947-6539",

publisher = "Wiley",

number = "2",

}

TY - JOUR

T1 - Polymeric organometallic architectures of novel P-Se anions

AU - Shi, Weifeng

AU - Shafaei-Fallah, Maryam

AU - Zhang, Le

AU - Anson, Christopher E.

AU - Matern, Eberhard

AU - Rothenberger, Alexander

PY - 2007

Y1 - 2007

N2 - The characterisation of a series of compounds obtained from Woollins' reagent (W.R.) offers a novel approach to organometallic coordination polymers. The syntheses were achieved by nucleophilic ring-opening reactions of W.R. with metal salts and crystallisation using solvent-diffusion techniques. One-dimensional coordination polymers are formed as a result, and we demonstrate that the dimensionality of the polymers can be influenced by using hydrated metal salts or by the construction of heterometallic arrangements.

AB - The characterisation of a series of compounds obtained from Woollins' reagent (W.R.) offers a novel approach to organometallic coordination polymers. The syntheses were achieved by nucleophilic ring-opening reactions of W.R. with metal salts and crystallisation using solvent-diffusion techniques. One-dimensional coordination polymers are formed as a result, and we demonstrate that the dimensionality of the polymers can be influenced by using hydrated metal salts or by the construction of heterometallic arrangements.

KW - Alkali metals

KW - Phosphorus

KW - Polymers

KW - Selenium

KW - Supramolecular chemistry

UR - http://www.scopus.com/inward/record.url?scp=33846245589&partnerID=8YFLogxK

U2 - 10.1002/chem.200600626

DO - 10.1002/chem.200600626

M3 - Article

C2 - 17013962

AN - SCOPUS:33846245589

SN - 0947-6539

VL - 13

SP - 598

EP - 603

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

IS - 2

ER -

Polymeric organometallic architectures of novel P-Se anions

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this