Polymer and Membrane Design for Low Temperature Catalytic Reactions

Luis Francisco Villalobos, Yihui Xie, Suzana Pereira Nunes, Klaus-Viktor Peinemann

Research output: Contribution to journalArticlepeer-review

14 Scopus citations


Catalytically active asymmetric membranes have been developed with high loadings of palladium nanoparticles located solely in the membrane's ultrathin skin layer. The manufacturing of these membranes requires polymers with functional groups, which can form insoluble complexes with palladium ions. Three polymers have been synthesized for this purpose and a complexation/nonsolvent induced phase separation followed by a palladium reduction step is carried out to prepare such membranes. Parameters to optimize the skin layer thickness and porosity, the palladium loading in this layer, and the palladium nanoparticles size are determined. The catalytic activity of the membranes is verified with the reduction of a nitro-compound and with a liquid phase Suzuki-Miyaura coupling reaction. Very low reaction times are observed. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Original languageEnglish (US)
Pages (from-to)700-704
Number of pages5
JournalMacromolecular Rapid Communications
Issue number8
StatePublished - Feb 29 2016

Bibliographical note

KAUST Repository Item: Exported on 2020-10-01
Acknowledgements: Financial support from King Abdullah University of Science and Technology (KAUST) is gratefully acknowledged. The authors thank Maria Peredo Silva for the illustrations in Scheme 1 and the graphical abstract.


Dive into the research topics of 'Polymer and Membrane Design for Low Temperature Catalytic Reactions'. Together they form a unique fingerprint.

Cite this