Polyhomologation and ATRP: A Perfect Partnership toward Unique Polyethylene-Based Architectures

De Wang; Zhen Zhang; Hefeng Zhang; Yves Gnanou; Nikos Hadjichristidis

doi:10.1021/bk-2018-1285.ch001

Polyhomologation and ATRP: A Perfect Partnership toward Unique Polyethylene-Based Architectures

De Wang, Zhen Zhang, Hefeng Zhang, Yves Gnanou, Nikos Hadjichristidis

Research output: Chapter in Book/Report/Conference proceeding › Chapter

1 Scopus citations

Abstract

The recent developments in organoborane initiated C1 polymerization (chain grows by one atom at a time) of ylides opens unique horizons towards well-defined/perfectly linear polymethylenes (equivalent to polyethylenes, PE). On the other hand, atom transfer radical polymerization (ATRP) is an excellent and powerful controlled/living polymerization for polar monomers such as (meth)acrylates and styrenes. In this Chapter the partnership of these two living polymerizations towards the synthesis of well-defined PE (perfectly linear)-based block copolymers, with unprecedented macromolecular architectures, is presented. Some ideas about new ylide monomers are also discussed.

Original language	English (US)
Title of host publication	Reversible Deactivation Radical Polymerization: Materials and Applications
Publisher	American Chemical Society (ACS)
Pages	1-24
Number of pages	24
ISBN (Print)	0841233233
DOIs	https://doi.org/10.1021/bk-2018-1285.ch001
State	Published - Aug 13 2018

Bibliographical note

KAUST Repository Item: Exported on 2020-10-01
Acknowledgements: Research reported in this publication was supported by the King Abdullah University of Science and Technology (KAUST).

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10.1021/bk-2018-1285.ch001

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abstract = "The recent developments in organoborane initiated C1 polymerization (chain grows by one atom at a time) of ylides opens unique horizons towards well-defined/perfectly linear polymethylenes (equivalent to polyethylenes, PE). On the other hand, atom transfer radical polymerization (ATRP) is an excellent and powerful controlled/living polymerization for polar monomers such as (meth)acrylates and styrenes. In this Chapter the partnership of these two living polymerizations towards the synthesis of well-defined PE (perfectly linear)-based block copolymers, with unprecedented macromolecular architectures, is presented. Some ideas about new ylide monomers are also discussed.",

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Polyhomologation and ATRP: A Perfect Partnership toward Unique Polyethylene-Based Architectures

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