Poly(Anthraquinonyl Sulfide)/CNT Composites as High-Rate-Performance Cathodes for Nonaqueous Rechargeable Calcium-Ion Batteries

Siqi Zhang, Youliang Zhu, Denghu Wang, Chunguang Li, Yu Han, Zhan Shi, Shouhua Feng

Research output: Contribution to journalArticlepeer-review

20 Scopus citations


Calcium-ion batteries (CIBs) are considered as promising alternatives in large-scale energy storage due to their divalent electron redox properties, low cost, and high volumetric/gravimetric capacity. However, the high charge density of Ca2+ contributes to strong electrostatic interaction between divalent Ca2+ and hosting lattice, leading to sluggish kinetics and poor rate performance. Here, in situ formed poly(anthraquinonyl sulfide) (PAQS)@CNT composite is reported as nonaqueous calcium-ion battery cathode. The enolization redox chemistry of organics has fast redox kinetics, and the introduction of carbon nanotube (CNT) accelerates electron transportation, which contributes to fast ionic diffusion. As the conductivity of the PAQS is enhanced by the increasing content of CNT, the voltage gap is significantly reduced. The PAQS@CNT electrode exhibits specific capacity (116 mAh g−1 at 0.05 A g−1), high rate capacity (60 mAh g−1 at 4 A g−1), and an initial capacity of 82 mAh g−1 at 1 A g−1 (83% capacity retention after 500 cycles). The electrochemical mechanism is proved to be that the PAQS undergoes reduction reaction of their carbonyl bond during discharge and becomes coordinated by Ca2+ and Ca(TFSI)+ species. Computational simulation also suggests that the construction of Ca2+ and Ca(TFSI)+ co-intercalation in the PAQS is the most reasonable pathway.
Original languageEnglish (US)
Pages (from-to)2200397
JournalAdvanced Science
StatePublished - Mar 20 2022

Bibliographical note

KAUST Repository Item: Exported on 2022-04-21
Acknowledgements: Financially supported by the National Natural Science Foundation of China (Grant Nos. 21771077, 21621001, and 21771084), the Foundation of Science and Technology Development of Jilin Province, China (Grant No. 20200801004GH), and 111 Project (Project No. B17020). The authors also gratefully acknowledge the financial support by the program for JLU Science and Technology Innovative Research Team (JLUSTIRT).


Dive into the research topics of 'Poly(Anthraquinonyl Sulfide)/CNT Composites as High-Rate-Performance Cathodes for Nonaqueous Rechargeable Calcium-Ion Batteries'. Together they form a unique fingerprint.

Cite this