Poly[(μ3-hydrogenphosphato)(4H-1,2,4-triazole-κN 1)zinc]

Hafid Aitenneite; Abdeslam El Bouari; Said Sebti; Mohamed Saadi; Lahcen El Ammari; Karim Adil

doi:10.1107/S1600536812044182

Poly[(μ₃-hydrogenphosphato)(4H-1,2,4-triazole-κN ¹)zinc]

Hafid Aitenneite^*, Abdeslam El Bouari, Said Sebti, Mohamed Saadi, Lahcen El Ammari, Karim Adil

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

The asymmetric unit of the title compound, [Zn(HPO₄)(C ₂H₃N₃)] n , contains one Zn²⁺ cation, one (HPO₄)^2- anion and a 1,2,4 triazole ligand. The Zn²⁺ cation is coordinated in a quite regular tetrahedral geometry by O atoms from three phosphate groups and a tertiary N atom from the triazole ring. Each phosphate anion is connected to three Zn^II cations, leading to a series of corrugated organic-inorganic layers parallel to the ac plane. The overall structure involves stacking of complex hybrid organic-inorganic layers along the b axis. Cohesion in the crystal is ensured by an infinite three-dimensional network of N-H⋯O and O-H⋯O hydrogen bonds between the phosphate groups and the triazole ligands.

Original language	English (US)
Pages (from-to)	m1426-m1427
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	68
Issue number	11
DOIs	https://doi.org/10.1107/S1600536812044182
State	Published - Nov 2012
Externally published	Yes

Keywords

R factor = 0.021
T = 296 K
data-to-parameter ratio = 33.2
mean ̄(N-C) = 0.002 Å
single-crystal X-ray study
wR factor = 0.051

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

Access to Document

10.1107/S1600536812044182

Cite this

@article{c4a81e11f9ab4243a74754f13ba91f33,

title = "Poly[(μ3-hydrogenphosphato)(4H-1,2,4-triazole-κN 1)zinc]",

abstract = "The asymmetric unit of the title compound, [Zn(HPO4)(C 2H3N3)] n , contains one Zn2+ cation, one (HPO4)2- anion and a 1,2,4 triazole ligand. The Zn2+ cation is coordinated in a quite regular tetrahedral geometry by O atoms from three phosphate groups and a tertiary N atom from the triazole ring. Each phosphate anion is connected to three ZnII cations, leading to a series of corrugated organic-inorganic layers parallel to the ac plane. The overall structure involves stacking of complex hybrid organic-inorganic layers along the b axis. Cohesion in the crystal is ensured by an infinite three-dimensional network of N-H⋯O and O-H⋯O hydrogen bonds between the phosphate groups and the triazole ligands.",

keywords = "R factor = 0.021, T = 296 K, data-to-parameter ratio = 33.2, mean{\= }(N-C) = 0.002 {\AA}, single-crystal X-ray study, wR factor = 0.051",

author = "Hafid Aitenneite and {El Bouari}, Abdeslam and Said Sebti and Mohamed Saadi and {El Ammari}, Lahcen and Karim Adil",

year = "2012",

month = nov,

doi = "10.1107/S1600536812044182",

language = "English (US)",

volume = "68",

pages = "m1426--m1427",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "11",

}

TY - JOUR

T1 - Poly[(μ3-hydrogenphosphato)(4H-1,2,4-triazole-κN 1)zinc]

AU - Aitenneite, Hafid

AU - El Bouari, Abdeslam

AU - Sebti, Said

AU - Saadi, Mohamed

AU - El Ammari, Lahcen

AU - Adil, Karim

PY - 2012/11

Y1 - 2012/11

N2 - The asymmetric unit of the title compound, [Zn(HPO4)(C 2H3N3)] n , contains one Zn2+ cation, one (HPO4)2- anion and a 1,2,4 triazole ligand. The Zn2+ cation is coordinated in a quite regular tetrahedral geometry by O atoms from three phosphate groups and a tertiary N atom from the triazole ring. Each phosphate anion is connected to three ZnII cations, leading to a series of corrugated organic-inorganic layers parallel to the ac plane. The overall structure involves stacking of complex hybrid organic-inorganic layers along the b axis. Cohesion in the crystal is ensured by an infinite three-dimensional network of N-H⋯O and O-H⋯O hydrogen bonds between the phosphate groups and the triazole ligands.

AB - The asymmetric unit of the title compound, [Zn(HPO4)(C 2H3N3)] n , contains one Zn2+ cation, one (HPO4)2- anion and a 1,2,4 triazole ligand. The Zn2+ cation is coordinated in a quite regular tetrahedral geometry by O atoms from three phosphate groups and a tertiary N atom from the triazole ring. Each phosphate anion is connected to three ZnII cations, leading to a series of corrugated organic-inorganic layers parallel to the ac plane. The overall structure involves stacking of complex hybrid organic-inorganic layers along the b axis. Cohesion in the crystal is ensured by an infinite three-dimensional network of N-H⋯O and O-H⋯O hydrogen bonds between the phosphate groups and the triazole ligands.

KW - R factor = 0.021

KW - T = 296 K

KW - data-to-parameter ratio = 33.2

KW - mean ̄(N-C) = 0.002 Å

KW - single-crystal X-ray study

KW - wR factor = 0.051

UR - http://www.scopus.com/inward/record.url?scp=84870867199&partnerID=8YFLogxK

U2 - 10.1107/S1600536812044182

DO - 10.1107/S1600536812044182

M3 - Article

C2 - 23284388

AN - SCOPUS:84870867199

SN - 1600-5368

VL - 68

SP - m1426-m1427

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 11

ER -