Abstract
The asymmetric unit of the title compound, [Zn(HPO4)(C 2H3N3)] n , contains one Zn2+ cation, one (HPO4)2- anion and a 1,2,4 triazole ligand. The Zn2+ cation is coordinated in a quite regular tetrahedral geometry by O atoms from three phosphate groups and a tertiary N atom from the triazole ring. Each phosphate anion is connected to three ZnII cations, leading to a series of corrugated organic-inorganic layers parallel to the ac plane. The overall structure involves stacking of complex hybrid organic-inorganic layers along the b axis. Cohesion in the crystal is ensured by an infinite three-dimensional network of N-H⋯O and O-H⋯O hydrogen bonds between the phosphate groups and the triazole ligands.
Original language | English (US) |
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Pages (from-to) | m1426-m1427 |
Journal | Acta Crystallographica Section E: Structure Reports Online |
Volume | 68 |
Issue number | 11 |
DOIs | |
State | Published - Nov 2012 |
Externally published | Yes |
Keywords
- R factor = 0.021
- T = 296 K
- data-to-parameter ratio = 33.2
- mean ̄(N-C) = 0.002 Å
- single-crystal X-ray study
- wR factor = 0.051
ASJC Scopus subject areas
- General Chemistry
- General Materials Science
- Condensed Matter Physics