Photoorganocatalysed and visible light photoredox catalysed trifluoromethylation of olefins and (hetero)aromatics in batch and continuous flow

Quentin Lefebvre; Norbert Hoffmann; Magnus Rueping

doi:10.1039/c5cc09881e

Photoorganocatalysed and visible light photoredox catalysed trifluoromethylation of olefins and (hetero)aromatics in batch and continuous flow

Quentin Lefebvre^*, Norbert Hoffmann, Magnus Rueping

^*Corresponding author for this work

Physical Sciences and Engineering

Research output: Contribution to journal › Article › peer-review

123 Scopus citations

Abstract

Trifluoromethylation of olefins and (hetero)aromatics with sodium triflinate as CF₃ source and readily accessible benzophenone derivatives as photosensitisers has been developed in batch and flow. The use of an iridium-based photocatalyst enables the trifluoromethylation to proceed under visible light irradiation.

Original language	English (US)
Pages (from-to)	2493-2496
Number of pages	4
Journal	CHEMICAL COMMUNICATIONS
Volume	52
Issue number	12
DOIs	https://doi.org/10.1039/c5cc09881e
State	Published - 2016

Bibliographical note

Publisher Copyright:
© 2016 The Royal Society of Chemistry.

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/c5cc09881e

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title = "Photoorganocatalysed and visible light photoredox catalysed trifluoromethylation of olefins and (hetero)aromatics in batch and continuous flow",

abstract = "Trifluoromethylation of olefins and (hetero)aromatics with sodium triflinate as CF3 source and readily accessible benzophenone derivatives as photosensitisers has been developed in batch and flow. The use of an iridium-based photocatalyst enables the trifluoromethylation to proceed under visible light irradiation.",

author = "Quentin Lefebvre and Norbert Hoffmann and Magnus Rueping",

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AU - Rueping, Magnus

PY - 2016

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AB - Trifluoromethylation of olefins and (hetero)aromatics with sodium triflinate as CF3 source and readily accessible benzophenone derivatives as photosensitisers has been developed in batch and flow. The use of an iridium-based photocatalyst enables the trifluoromethylation to proceed under visible light irradiation.

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Photoorganocatalysed and visible light photoredox catalysed trifluoromethylation of olefins and (hetero)aromatics in batch and continuous flow

Abstract

Bibliographical note

ASJC Scopus subject areas

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