PHOTO-FRIES REARRANGEMENT AND ITS USE IN POLYMERIC IMAGING SYSTEMS.

T. G. Tessier; Jean Frechet; C. G. Willson; H. Ito

PHOTO-FRIES REARRANGEMENT AND ITS USE IN POLYMERIC IMAGING SYSTEMS.

T. G. Tessier^*, Jean Frechet, C. G. Willson, H. Ito

^*Corresponding author for this work

Physical Sciences and Engineering

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

2 Scopus citations

Abstract

The lithographic potential of the photo-Fries reaction rests on the ability to selectively dissolve either the exposed or the unexposed areas of a polymer film. Typically, it is expected that in the case of polymers containing phenolic ester groups, the photoproducts, being substituted phenols, should dissolve in aqueous base while the unchanged starting polymer should remain undissolved. Similar results should also be within reach using the photo-Fries reaction on polymers containing aromatic amide groups. Although it is anticipated that, in some cases, the photostabilizing effect of the rearrangement products might have a deleterious effect on the imaging characteristics of the polymers, it is nevertheless likely that imaging of thin films should remain possible. The polymers used in this study included poly(p-acetoxystyrene), poly(p-formyloxystyrene), poly(p-acetamidostyrene), poly(phenyl methacrylate), and poly(methacryl anilide).

Original language	English (US)
Title of host publication	ACS Symposium Series
Editors	L.F. Thompson, C.G. Willson, J.M.J. Frechet
Publisher	ACS
Pages	269-292
Number of pages	24
Edition	266
ISBN (Print)	0841208719
State	Published - Dec 1 1984

Publication series

Name	ACS Symposium Series
Number	266
ISSN (Print)	0097-6156

ASJC Scopus subject areas

Chemistry(all)
Chemical Engineering(all)

Cite this

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title = "PHOTO-FRIES REARRANGEMENT AND ITS USE IN POLYMERIC IMAGING SYSTEMS.",

abstract = "The lithographic potential of the photo-Fries reaction rests on the ability to selectively dissolve either the exposed or the unexposed areas of a polymer film. Typically, it is expected that in the case of polymers containing phenolic ester groups, the photoproducts, being substituted phenols, should dissolve in aqueous base while the unchanged starting polymer should remain undissolved. Similar results should also be within reach using the photo-Fries reaction on polymers containing aromatic amide groups. Although it is anticipated that, in some cases, the photostabilizing effect of the rearrangement products might have a deleterious effect on the imaging characteristics of the polymers, it is nevertheless likely that imaging of thin films should remain possible. The polymers used in this study included poly(p-acetoxystyrene), poly(p-formyloxystyrene), poly(p-acetamidostyrene), poly(phenyl methacrylate), and poly(methacryl anilide).",

author = "Tessier, {T. G.} and Jean Frechet and Willson, {C. G.} and H. Ito",

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T1 - PHOTO-FRIES REARRANGEMENT AND ITS USE IN POLYMERIC IMAGING SYSTEMS.

AU - Tessier, T. G.

AU - Frechet, Jean

AU - Willson, C. G.

AU - Ito, H.

PY - 1984/12/1

Y1 - 1984/12/1

N2 - The lithographic potential of the photo-Fries reaction rests on the ability to selectively dissolve either the exposed or the unexposed areas of a polymer film. Typically, it is expected that in the case of polymers containing phenolic ester groups, the photoproducts, being substituted phenols, should dissolve in aqueous base while the unchanged starting polymer should remain undissolved. Similar results should also be within reach using the photo-Fries reaction on polymers containing aromatic amide groups. Although it is anticipated that, in some cases, the photostabilizing effect of the rearrangement products might have a deleterious effect on the imaging characteristics of the polymers, it is nevertheless likely that imaging of thin films should remain possible. The polymers used in this study included poly(p-acetoxystyrene), poly(p-formyloxystyrene), poly(p-acetamidostyrene), poly(phenyl methacrylate), and poly(methacryl anilide).

AB - The lithographic potential of the photo-Fries reaction rests on the ability to selectively dissolve either the exposed or the unexposed areas of a polymer film. Typically, it is expected that in the case of polymers containing phenolic ester groups, the photoproducts, being substituted phenols, should dissolve in aqueous base while the unchanged starting polymer should remain undissolved. Similar results should also be within reach using the photo-Fries reaction on polymers containing aromatic amide groups. Although it is anticipated that, in some cases, the photostabilizing effect of the rearrangement products might have a deleterious effect on the imaging characteristics of the polymers, it is nevertheless likely that imaging of thin films should remain possible. The polymers used in this study included poly(p-acetoxystyrene), poly(p-formyloxystyrene), poly(p-acetamidostyrene), poly(phenyl methacrylate), and poly(methacryl anilide).

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M3 - Conference contribution

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T3 - ACS Symposium Series

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A2 - Thompson, L.F.

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A2 - Frechet, J.M.J.

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PHOTO-FRIES REARRANGEMENT AND ITS USE IN POLYMERIC IMAGING SYSTEMS.

Abstract

Publication series

ASJC Scopus subject areas

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