Palladium N-Heterocyclic Carbene Precatalyst Site Isolated in the Core of a Star Polymer

Konstantin Bukhriakov; Clement Mugemana; Khanh B. Vu; Valentin Rodionov

doi:10.1021/acs.orglett.5b02388

Palladium N-Heterocyclic Carbene Precatalyst Site Isolated in the Core of a Star Polymer

Konstantin Bukhriakov, Clement Mugemana, Khanh B. Vu, Valentin Rodionov

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Abstract

An approach for supporting a Pd-NHC complex on a soluble star polymer with nanoscale dimensions is described. The resulting star polymer catalyst exhibits excellent activity in cross-coupling reactions, is stable in air and moisture, and is easily recoverable and recyclable. These properties are distinct and unattainable with the small-molecule version of the same catalyst. © 2015 American Chemical Society.

Original language	English (US)
Pages (from-to)	4826-4829
Number of pages	4
Journal	Organic Letters
Volume	17
Issue number	19
DOIs	https://doi.org/10.1021/acs.orglett.5b02388
State	Published - Sep 23 2015

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KAUST Repository Item: Exported on 2020-10-01
Acknowledgements: King Abdullah University of Science and Technology

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abstract = "An approach for supporting a Pd-NHC complex on a soluble star polymer with nanoscale dimensions is described. The resulting star polymer catalyst exhibits excellent activity in cross-coupling reactions, is stable in air and moisture, and is easily recoverable and recyclable. These properties are distinct and unattainable with the small-molecule version of the same catalyst. {\textcopyright} 2015 American Chemical Society.",

author = "Konstantin Bukhriakov and Clement Mugemana and Vu, {Khanh B.} and Valentin Rodionov",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: King Abdullah University of Science and Technology",

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AU - Bukhriakov, Konstantin

AU - Mugemana, Clement

AU - Vu, Khanh B.

AU - Rodionov, Valentin

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: King Abdullah University of Science and Technology

PY - 2015/9/23

Y1 - 2015/9/23

N2 - An approach for supporting a Pd-NHC complex on a soluble star polymer with nanoscale dimensions is described. The resulting star polymer catalyst exhibits excellent activity in cross-coupling reactions, is stable in air and moisture, and is easily recoverable and recyclable. These properties are distinct and unattainable with the small-molecule version of the same catalyst. © 2015 American Chemical Society.

AB - An approach for supporting a Pd-NHC complex on a soluble star polymer with nanoscale dimensions is described. The resulting star polymer catalyst exhibits excellent activity in cross-coupling reactions, is stable in air and moisture, and is easily recoverable and recyclable. These properties are distinct and unattainable with the small-molecule version of the same catalyst. © 2015 American Chemical Society.

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EP - 4829

JO - Organic Letters

JF - Organic Letters

IS - 19

ER -

Palladium N-Heterocyclic Carbene Precatalyst Site Isolated in the Core of a Star Polymer

Abstract

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