Oxidative dimerization of methane: a surface organometallic approach to lithium doped magnesia or silica catalysts

Ch Chevalier; P. Ramirez de la Piscina; M. Ceruso; A. Choplin; J. M. Basset

doi:10.1016/0920-5861(89)85039-4

Oxidative dimerization of methane: a surface organometallic approach to lithium doped magnesia or silica catalysts

Ch Chevalier^*, P. Ramirez de la Piscina, M. Ceruso, A. Choplin, J. M. Basset

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

15 Scopus citations

Abstract

Silica doped with Mg or Li and magnesia doped with Li have been prepared via organometallics i.e. bis-(neopentyl)-magnesium and neopentyl-(lithium). The catalytic activity of these solids has been studied for the oxidative dimerization of methane and compared to a magnesia doped with Li₂CO₃. The importance of parameters such as reactor walls, support, presence of an anion is discussed.

Original language	English (US)
Pages (from-to)	433-439
Number of pages	7
Journal	Catalysis Today
Volume	4
Issue number	3-4
DOIs	https://doi.org/10.1016/0920-5861(89)85039-4
State	Published - Feb 1989
Externally published	Yes

ASJC Scopus subject areas

Catalysis
General Chemistry

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abstract = "Silica doped with Mg or Li and magnesia doped with Li have been prepared via organometallics i.e. bis-(neopentyl)-magnesium and neopentyl-(lithium). The catalytic activity of these solids has been studied for the oxidative dimerization of methane and compared to a magnesia doped with Li2CO3. The importance of parameters such as reactor walls, support, presence of an anion is discussed.",

author = "Ch Chevalier and {de la Piscina}, {P. Ramirez} and M. Ceruso and A. Choplin and Basset, {J. M.}",

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T2 - a surface organometallic approach to lithium doped magnesia or silica catalysts

AU - Chevalier, Ch

AU - de la Piscina, P. Ramirez

AU - Ceruso, M.

AU - Choplin, A.

AU - Basset, J. M.

PY - 1989/2

Y1 - 1989/2

N2 - Silica doped with Mg or Li and magnesia doped with Li have been prepared via organometallics i.e. bis-(neopentyl)-magnesium and neopentyl-(lithium). The catalytic activity of these solids has been studied for the oxidative dimerization of methane and compared to a magnesia doped with Li2CO3. The importance of parameters such as reactor walls, support, presence of an anion is discussed.

AB - Silica doped with Mg or Li and magnesia doped with Li have been prepared via organometallics i.e. bis-(neopentyl)-magnesium and neopentyl-(lithium). The catalytic activity of these solids has been studied for the oxidative dimerization of methane and compared to a magnesia doped with Li2CO3. The importance of parameters such as reactor walls, support, presence of an anion is discussed.

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U2 - 10.1016/0920-5861(89)85039-4

DO - 10.1016/0920-5861(89)85039-4

M3 - Article

AN - SCOPUS:0024608556

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JO - Catalysis Today

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ER -

Oxidative dimerization of methane: a surface organometallic approach to lithium doped magnesia or silica catalysts

Abstract

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