Orthogonal Lithography for Halide Perovskite Optoelectronic Nanodevices

Chun-Ho Lin, Bin Cheng, Ting-You Li, Jose Ramon Duran Retamal, Tzu-Chiao Wei, Hui-Chun Fu, Xiaosheng Fang, Jr-Hau He

Research output: Contribution to journalArticlepeer-review

127 Scopus citations

Abstract

3D organic–inorganic hybrid halide perovskites have attracted great interest due to their impressive optoelectronic properties. Recently, the emergence of 2D layered hybrid perovskites, with their excellent and tunable optoelectronic behavior, has encouraged researchers to develop the next generation of optoelectronics based on these 2D materials. However, device fabrication methods of scalable patterning on both types of hybrid perovskites are still lacking as these materials are readily damaged by the organic solvents in standard lithographic processes. We conceived the orthogonal processing and patterning method: Chlorobenzene and hexane, which are orthogonal to hybrid perovskites, are utilized in modified electron beam lithography (EBL) processes to fabricate perovskite-based devices without compromising their electronic or optical characteristics. As a proof-of-concept, we used the orthogonal EBL technique to fabricate a 2D layered single-crystal (C6H5C2H4NH3)2PbI4 photodetector featuring nanoscale patterned electrodes and superior photodetection ability with responsivity of 5.4 mA/W and detectivity of 1.07 × 1013 cm Hz1/2/W. Such orthogonal processing and patterning methods are believed to fully enable the high-resolution, high-throughput fabrication of complex perovskite-based electronics in the near future.
Original languageEnglish (US)
Pages (from-to)1168-1176
Number of pages9
JournalACS Nano
Volume13
Issue number2
DOIs
StatePublished - Dec 31 2018

Bibliographical note

KAUST Repository Item: Exported on 2020-10-01
Acknowledged KAUST grant number(s): OSR-2016-CRG5-3005, FCC/1/3079-08-01
Acknowledgements: This work was financially supported by the King Abdullah University of Science and Technology (KAUST) Office of Sponsored Research (OSR) (OSR-2016-CRG5-3005), KAUST solar center (FCC/1/3079-08-01), and KAUST baseline funding. X.F. acknowledges the support from Science and Technology Commission of Shanghai Municipality (18520744600, 18520710800, and 17520742400).

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