Organocatalytic conjugate-addition polymerization of linear and cyclic acrylic monomers by N-heterocyclic carbenes: Mechanisms of chain initiation, propagation, and termination

Chemistry

• Addition Polymerization 50%
• Adduct 16%
• Ambient Reaction Temperature 16%
• Biomass 16%
• Catalyst 16%
• Chemical Reaction 16%
• Dimerization 50%
• Enamine 33%
• Energy 16%
• Initiator 16%
• Methyl 100%
• Methyl Methacrylate 33%
• Molecular Mass 33%
• Monomer 83%
• N-Heterocyclic Carbene 100%
• Nucleophilicity 16%
• Organocatalysis 33%
• Polarity 16%
• Polymer 16%
• Polymerization Reaction 83%
• Proton Transfer 16%
• Reaction Selectivity 33%
• Reactivity 16%
• Solvent 16%
• Structure 33%
• Turnover Frequency 16%