Ordering effects in benzo[1,2-b:4,5-b']difuran-thieno[3,4-c]pyrrole-4,6- dione polymers with >7% solar cell efficiency

Julien Warnan, Clement Cabanetos, Abdulrahman El Labban, Michael Ryan Hansen, Christopher J. Tassone, Michael F. Toney, Pierre Beaujuge

Research output: Contribution to journalArticlepeer-review

87 Scopus citations

Abstract

Benzo[1,2-b:4,5-b']difuran-thieno[3,4-c]pyrrole-4,6-dione (PBDFTPD) polymers prepared by microwave-assisted synthesis can achieve power conversion efficiencies (PCEs) >7% in bulk-heterojunction solar cells with phenyl-C61/71-butyric acid methyl ester (PCBM). In "as-cast" PBDFTPD-based devices solution-processed without a small-molecule additive, high PCEs can be obtained in spite of the weak propensity of the polymers to self-assemble and form π-aggregates in thin films. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Original languageEnglish (US)
Pages (from-to)4357-4362
Number of pages6
JournalAdvanced Materials
Volume26
Issue number25
DOIs
StatePublished - May 15 2014

Bibliographical note

KAUST Repository Item: Exported on 2020-10-01
Acknowledgements: The authors acknowledge financial support under Baseline Research Funding from King Abdullah University of Science and Technology (KAUST). The authors thank KAUST Analytical Core Labs for mass spectrometry and elemental analyses, and Sandra Seywald (MPIP - Mainz, Germany) for SEC measurements. The authors thank the Advanced Imaging and Characterization Laboratories at KAUST for technical support. Portions of this research were carried out at the Stanford Synchrotron Radiation Lightsource user facility, operated by Stanford University on behalf of the U.S. Department of Energy, Office of Basic Energy Sciences. MRH acknowledges financial support from the Villum Foundation under the Young Investigator Program.

ASJC Scopus subject areas

  • Mechanics of Materials
  • Materials Science(all)
  • Mechanical Engineering

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