Optimal Interfacial Band Bending Achieved by Fine Energy Level Tuning in Mixed-Halide Perovskite Solar Cells

Matyas Daboczi, Sinclair R. Ratnasingham, Lokeshwari Mohan, Chenfeng Pu, Iain Hamilton, Yi-Chun Chin, Martyn A. McLachlan, Ji Seon Kim

Research output: Contribution to journalArticlepeer-review

7 Scopus citations

Abstract

Most highly efficient perovskite solar cells employ mixed iodide–bromide photoactive layers; however, understanding the beneficial effect of the low (5–15 mol %) bromide content is incomplete. Here, a series of MAPb(I1–xBrx)3 perovskite layers are investigated to understand the origin of the high peak power conversion efficiency (19.2%) observed at small bromide content (0.10 ≤ x ≤ 0.125). For the x = 0.125 perovskite, 200 meV shallower energy levels are revealed, accompanied by a reduced density of trap states and stable tetragonal mixed-halide phase with compressed unit cell. In contrast, the higher bromide content samples (x > 0.125) show deeper energy levels, cubic perovskite crystal structure, and signs of halide segregation. Surface photovoltage measurements unveil an undesirable band bending at the hole transport layer/perovskite interface for MAPbI3 and x > 0.125 mixed-halide layers, which is eliminated for the x = 0.125 perovskite because of its shallower Fermi level, enabling enhanced device performance.
Original languageEnglish (US)
Pages (from-to)3970-3981
Number of pages12
JournalACS Energy Letters
DOIs
StatePublished - Oct 21 2021

Bibliographical note

KAUST Repository Item: Exported on 2021-10-25
Acknowledgements: The authors acknowledge the funding of UK Engineering and Physical Sciences Research Council (EPSRC) Plastic Electronics Doctoral Training Centre (EP/L016702/1) and KP Technology Ltd for EPSRC CASE studentships. This research was also supported by the UK EPSRC ATIP Programme Grant (EP/T028513/1) and the Global Research Laboratory Program of the National Research Foundation (NRF) funded by the Ministry of Science, ICT & Future Planning (NRF-2017K1A1A2 013153).

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