On the equivalence of the Schrödinger and the quantum Liouville equations

We present a semigroup analysis of the quantum Liouville equation, which models the temporal evolution of the (quasi) distribution of an electron ensemble under the action of a scalar potential. By employing the density matrix formulation of quantum physics we prove that the quantum Liouville operator generates a unitary group on L² if the corresponding Hamiltonian is essentially self‐adjoint. Also, we analyse the existence and non‐negativity of the particale density and prove that the solutions of the quantum Liouville equation converge to weak solutions of the classical Liouville equation as the Planck constant tends to zero (assuming that the potential is sufficiently smooth).