O2- -to-F- substitution on the quasi-two-dimensional quantum antiferromagnet (CuCl)LaNb2O7

C. Tassel; Y. Kobayashi; S. Mitsuoka; F. Takeiri; Y. Ajiro; H. Kageyama

doi:10.1088/1742-6596/320/1/012036

O2- -to-F- substitution on the quasi-two-dimensional quantum antiferromagnet (CuCl)LaNb2O7

C. Tassel, Y. Kobayashi, S. Mitsuoka, F. Takeiri, Y. Ajiro, H. Kageyama

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

Abstract

We present the preparation of the electron-doped quasi-two dimensional quantum antiferromagnet (CuCl)LaNb2O7 by two step-wise topochemical reactions. The first step involves a reductive fluorination of the insulating layered perovskite RbLaNb2O7 using polytetrafluoroethylene that allows electric conduction in the perovskite blocks. The product RbLaNb2O6F was then ion-exchanged with copper dichloride to yield (CuCl)LaNb2O6F. The synchrotron x-ray diffraction study indicates that the structure of the final compound is different from that of the pure (CuCl)LaNb2O7. © 2011 Published under licence by IOP Publishing Ltd.

Original language	English (US)
Title of host publication	Journal of Physics: Conference Series
Publisher	Institute of Physics Publishinghelen.craven@iop.org
DOIs	https://doi.org/10.1088/1742-6596/320/1/012036
State	Published - Jan 1 2011
Externally published	Yes

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Generated from Scopus record by KAUST IRTS on 2022-09-13

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title = "O2- -to-F- substitution on the quasi-two-dimensional quantum antiferromagnet (CuCl)LaNb2O7",

abstract = "We present the preparation of the electron-doped quasi-two dimensional quantum antiferromagnet (CuCl)LaNb2O7 by two step-wise topochemical reactions. The first step involves a reductive fluorination of the insulating layered perovskite RbLaNb2O7 using polytetrafluoroethylene that allows electric conduction in the perovskite blocks. The product RbLaNb2O6F was then ion-exchanged with copper dichloride to yield (CuCl)LaNb2O6F. The synchrotron x-ray diffraction study indicates that the structure of the final compound is different from that of the pure (CuCl)LaNb2O7. {\textcopyright} 2011 Published under licence by IOP Publishing Ltd.",

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doi = "10.1088/1742-6596/320/1/012036",

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T1 - O2- -to-F- substitution on the quasi-two-dimensional quantum antiferromagnet (CuCl)LaNb2O7

AU - Tassel, C.

AU - Kobayashi, Y.

AU - Mitsuoka, S.

AU - Takeiri, F.

AU - Ajiro, Y.

AU - Kageyama, H.

N1 - Generated from Scopus record by KAUST IRTS on 2022-09-13

PY - 2011/1/1

Y1 - 2011/1/1

N2 - We present the preparation of the electron-doped quasi-two dimensional quantum antiferromagnet (CuCl)LaNb2O7 by two step-wise topochemical reactions. The first step involves a reductive fluorination of the insulating layered perovskite RbLaNb2O7 using polytetrafluoroethylene that allows electric conduction in the perovskite blocks. The product RbLaNb2O6F was then ion-exchanged with copper dichloride to yield (CuCl)LaNb2O6F. The synchrotron x-ray diffraction study indicates that the structure of the final compound is different from that of the pure (CuCl)LaNb2O7. © 2011 Published under licence by IOP Publishing Ltd.

AB - We present the preparation of the electron-doped quasi-two dimensional quantum antiferromagnet (CuCl)LaNb2O7 by two step-wise topochemical reactions. The first step involves a reductive fluorination of the insulating layered perovskite RbLaNb2O7 using polytetrafluoroethylene that allows electric conduction in the perovskite blocks. The product RbLaNb2O6F was then ion-exchanged with copper dichloride to yield (CuCl)LaNb2O6F. The synchrotron x-ray diffraction study indicates that the structure of the final compound is different from that of the pure (CuCl)LaNb2O7. © 2011 Published under licence by IOP Publishing Ltd.

UR - https://iopscience.iop.org/article/10.1088/1742-6596/320/1/012036

UR - http://www.scopus.com/inward/record.url?scp=81055133431&partnerID=8YFLogxK

U2 - 10.1088/1742-6596/320/1/012036

DO - 10.1088/1742-6596/320/1/012036

M3 - Conference contribution

BT - Journal of Physics: Conference Series

PB - Institute of Physics Publishinghelen.craven@iop.org

ER -

O2- -to-F- substitution on the quasi-two-dimensional quantum antiferromagnet (CuCl)LaNb2O7

Abstract

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