O2- -to-F- substitution on the quasi-two-dimensional quantum antiferromagnet (CuCl)LaNb2O7

C. Tassel, Y. Kobayashi, S. Mitsuoka, F. Takeiri, Y. Ajiro, H. Kageyama

Research output: Chapter in Book/Report/Conference proceedingConference contribution


We present the preparation of the electron-doped quasi-two dimensional quantum antiferromagnet (CuCl)LaNb2O7 by two step-wise topochemical reactions. The first step involves a reductive fluorination of the insulating layered perovskite RbLaNb2O7 using polytetrafluoroethylene that allows electric conduction in the perovskite blocks. The product RbLaNb2O6F was then ion-exchanged with copper dichloride to yield (CuCl)LaNb2O6F. The synchrotron x-ray diffraction study indicates that the structure of the final compound is different from that of the pure (CuCl)LaNb2O7. © 2011 Published under licence by IOP Publishing Ltd.
Original languageEnglish (US)
Title of host publicationJournal of Physics: Conference Series
PublisherInstitute of Physics Publishinghelen.craven@iop.org
StatePublished - Jan 1 2011
Externally publishedYes

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