Novel styrene-butadiene copolymers by ring-opening metathesis polymerization

V. Héroguez; E. Amédro; D. Grande; M. Fontanille; Yves Gnanou

doi:10.1021/ma000470d

Novel styrene-butadiene copolymers by ring-opening metathesis polymerization

V. Héroguez^*, E. Amédro, D. Grande, M. Fontanille, Yves Gnanou

^*Corresponding author for this work

Physical Sciences and Engineering

Research output: Contribution to journal › Article › peer-review

46 Scopus citations

Abstract

The possibilities offered by the ring-opening metathesis polymerization (ROMP) of macromonomers were exploited to arrange polystyrene (PS) and polybutadiene (PB) subchains in various topologies. PS _n -b-PB _m and PS _n -co-PB _m miktoarm stars were obtained by sequential and statistical polymerization of norbornene-terminated PS and PB macromonomers, whereas (PS-b-PB) _n star block copolymers were derived by homopolymerization of the corresponding macromonomers via ROMP. Umbrella-type and dumbbell-shaped copolymers are two other architectures that were prepared through the sequential ROMP of ω-norbornenyl PS macromonomer and cyclooctadiene.

Original language	English (US)
Pages (from-to)	7241-7248
Number of pages	8
Journal	Macromolecules
Volume	33
Issue number	20
DOIs	https://doi.org/10.1021/ma000470d
State	Published - Oct 3 2000

ASJC Scopus subject areas

Organic Chemistry
Polymers and Plastics
Inorganic Chemistry
Materials Chemistry

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10.1021/ma000470d

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title = "Novel styrene-butadiene copolymers by ring-opening metathesis polymerization",

abstract = " The possibilities offered by the ring-opening metathesis polymerization (ROMP) of macromonomers were exploited to arrange polystyrene (PS) and polybutadiene (PB) subchains in various topologies. PS n -b-PB m and PS n -co-PB m miktoarm stars were obtained by sequential and statistical polymerization of norbornene-terminated PS and PB macromonomers, whereas (PS-b-PB) n star block copolymers were derived by homopolymerization of the corresponding macromonomers via ROMP. Umbrella-type and dumbbell-shaped copolymers are two other architectures that were prepared through the sequential ROMP of ω-norbornenyl PS macromonomer and cyclooctadiene. ",

author = "V. H{\'e}roguez and E. Am{\'e}dro and D. Grande and M. Fontanille and Yves Gnanou",

year = "2000",

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doi = "10.1021/ma000470d",

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T1 - Novel styrene-butadiene copolymers by ring-opening metathesis polymerization

AU - Héroguez, V.

AU - Amédro, E.

AU - Grande, D.

AU - Fontanille, M.

AU - Gnanou, Yves

PY - 2000/10/3

Y1 - 2000/10/3

N2 - The possibilities offered by the ring-opening metathesis polymerization (ROMP) of macromonomers were exploited to arrange polystyrene (PS) and polybutadiene (PB) subchains in various topologies. PS n -b-PB m and PS n -co-PB m miktoarm stars were obtained by sequential and statistical polymerization of norbornene-terminated PS and PB macromonomers, whereas (PS-b-PB) n star block copolymers were derived by homopolymerization of the corresponding macromonomers via ROMP. Umbrella-type and dumbbell-shaped copolymers are two other architectures that were prepared through the sequential ROMP of ω-norbornenyl PS macromonomer and cyclooctadiene.

AB - The possibilities offered by the ring-opening metathesis polymerization (ROMP) of macromonomers were exploited to arrange polystyrene (PS) and polybutadiene (PB) subchains in various topologies. PS n -b-PB m and PS n -co-PB m miktoarm stars were obtained by sequential and statistical polymerization of norbornene-terminated PS and PB macromonomers, whereas (PS-b-PB) n star block copolymers were derived by homopolymerization of the corresponding macromonomers via ROMP. Umbrella-type and dumbbell-shaped copolymers are two other architectures that were prepared through the sequential ROMP of ω-norbornenyl PS macromonomer and cyclooctadiene.

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U2 - 10.1021/ma000470d

DO - 10.1021/ma000470d

M3 - Article

AN - SCOPUS:0342572622

VL - 33

SP - 7241

EP - 7248

JO - Macromolecules

JF - Macromolecules

SN - 0024-9297

IS - 20

ER -

Novel styrene-butadiene copolymers by ring-opening metathesis polymerization

Abstract

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