TY - PAT
T1 - Novel imines with tunable nucleophilicity and steric properties through metal coordination: applications as ligands and metalloorganocatalysts
AU - Huang, Kuo-Wei
AU - Zhao, Qianyi
N1 - KAUST Repository Item: Exported on 2019-02-13
PY - 2016/3/17
Y1 - 2016/3/17
N2 - The invention describes phospho-amino pincer-type ligands, metal complexes thereof, and catalytic methods comprising such metal complexes for conversion of carbon dioxide to methanol, conversion of aldehydes into alcohols, conversion of aldehydes in the presence of a trifluoromethylation agent into trifluorinated secondary alcohols, cycloaddition of carbon dioxide to an epoxide to provide cyclic carbonates or preparation of an amide from the combination of an alcohol and an amine.
AB - The invention describes phospho-amino pincer-type ligands, metal complexes thereof, and catalytic methods comprising such metal complexes for conversion of carbon dioxide to methanol, conversion of aldehydes into alcohols, conversion of aldehydes in the presence of a trifluoromethylation agent into trifluorinated secondary alcohols, cycloaddition of carbon dioxide to an epoxide to provide cyclic carbonates or preparation of an amide from the combination of an alcohol and an amine.
UR - http://hdl.handle.net/10754/620478
UR - http://www.google.com/patents/WO2016038543A1
UR - http://worldwide.espacenet.com/publicationDetails/biblio?CC=WO&NR=2016038543A1&KC=A1&FT=D
M3 - Patent
M1 - WO 2016038543 A1
ER -