Novel amphiphilic architectures by ring-opening metathesis polymerization of macromonomers

Valerie Heroguez*, Yves Gnanou, Michel Fontanille

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

158 Scopus citations


In this study the possibilities offered by `living' ring-opening metathesis polymerization (ROMP) are exploited to engineer novel macromolecular architectures. It is indeed shown that amphiphilic branched structures of hitherto unreported topologies can be prepared by ROMP of miscellaneous macromonomers, provided the latter polymers carry an end-standing norbernene unsaturation. Janus-type architectures are, for instance, accessible by sequential ROMP of polystyrene (PS) and poly(ethylene oxide) (PEO) macromonomers; other original branched structures, whose topology makes them particularly attractive for applications such as unimolecular micelles or associative thickeners, can be obtained through homopolymerization of macromonomers based on PS-b-PEO diblock copolymers.

Original languageEnglish (US)
Pages (from-to)4791-4798
Number of pages8
Issue number17
StatePublished - Jan 1 1997

ASJC Scopus subject areas

  • Organic Chemistry
  • Polymers and Plastics
  • Inorganic Chemistry
  • Materials Chemistry


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