Structural features of localization of chiral isomers of 1-phenylethanol (R-PhEtOH and S-PhEtOH) and their mobility activation in homochiral metal-organic [Zn2(bdc)(S-lac)(dmf)] sorbent were studied with 1H and 13C NMR methods. 13C NMR chemical shifts do not show obvious advantage of selective interaction of molecule guests. But activation molecular mobility of S-PhEtOH and R-PhEtOH clearly indicates that stabilization of [Zn2(bdc)(S-lac)(dmf)]·S-PhEtOH structure is more preferable than stabilization of [Zn2(bdc)(S-lac)(dmf)]·R-PhEtOH structure.
- 1-phenylethanol enantiomers
- H and C NMR
- homochiral metal-organic sorbent
ASJC Scopus subject areas
- Materials Science(all)