Nitrogen-thermal modification of the bifunctional interfaces of transition metal/carbon dyads for the reversible hydrogenation and dehydrogenation of heteroarenes

Hui Su; Lu Han Sun; Zhong Hua Xue; Peng Gao; Shi Nan Zhang; Guang Yao Zhai; Yi Ming Zhang; Yun Xiao Lin; Xin Hao Li; Jie Sheng Chen

doi:10.1039/c9cc05114g

Nitrogen-thermal modification of the bifunctional interfaces of transition metal/carbon dyads for the reversible hydrogenation and dehydrogenation of heteroarenes

Hui Su, Lu Han Sun, Zhong Hua Xue, Peng Gao, Shi Nan Zhang, Guang Yao Zhai, Yi Ming Zhang, Yun Xiao Lin, Xin Hao Li^*, Jie Sheng Chen

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

A nitrogen-thermal approach via the reaction between transition metal species and N dopants affords us the ability to optimize the tradeoff between the number of exposed transition metal/carbon (exemplified by cobalt in this work) boundaries and the most pronounced interfacial rectifying contact to achieve the highly efficient and selective hydrogenation and dehydrogenation of N-heterocycle compounds in a reversible manner.

Original language	English (US)
Pages (from-to)	11394-11397
Number of pages	4
Journal	CHEMICAL COMMUNICATIONS
Volume	55
Issue number	76
DOIs	https://doi.org/10.1039/c9cc05114g
State	Published - 2019

Bibliographical note

Funding Information:
This work was supported by the National Natural Science Foundation of China (21722103, 21720102002, and 21673140) and the SJTU-MPI partner group. The authors thank the Shanghai Synchrotron Radiation Facility for providing beamtime (BL14W1).

Publisher Copyright:
© 2019 The Royal Society of Chemistry.

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/c9cc05114g

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Su, H., Sun, L. H., Xue, Z. H., Gao, P., Zhang, S. N., Zhai, G. Y., Zhang, Y. M., Lin, Y. X., Li, X. H., & Chen, J. S. (2019). Nitrogen-thermal modification of the bifunctional interfaces of transition metal/carbon dyads for the reversible hydrogenation and dehydrogenation of heteroarenes. CHEMICAL COMMUNICATIONS, 55(76), 11394-11397. https://doi.org/10.1039/c9cc05114g

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abstract = "A nitrogen-thermal approach via the reaction between transition metal species and N dopants affords us the ability to optimize the tradeoff between the number of exposed transition metal/carbon (exemplified by cobalt in this work) boundaries and the most pronounced interfacial rectifying contact to achieve the highly efficient and selective hydrogenation and dehydrogenation of N-heterocycle compounds in a reversible manner.",

author = "Hui Su and Sun, {Lu Han} and Xue, {Zhong Hua} and Peng Gao and Zhang, {Shi Nan} and Zhai, {Guang Yao} and Zhang, {Yi Ming} and Lin, {Yun Xiao} and Li, {Xin Hao} and Chen, {Jie Sheng}",

note = "Funding Information: This work was supported by the National Natural Science Foundation of China (21722103, 21720102002, and 21673140) and the SJTU-MPI partner group. The authors thank the Shanghai Synchrotron Radiation Facility for providing beamtime (BL14W1). Publisher Copyright: {\textcopyright} 2019 The Royal Society of Chemistry.",

year = "2019",

doi = "10.1039/c9cc05114g",

language = "English (US)",

volume = "55",

pages = "11394--11397",

journal = "CHEMICAL COMMUNICATIONS",

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T1 - Nitrogen-thermal modification of the bifunctional interfaces of transition metal/carbon dyads for the reversible hydrogenation and dehydrogenation of heteroarenes

AU - Su, Hui

AU - Sun, Lu Han

AU - Xue, Zhong Hua

AU - Gao, Peng

AU - Zhang, Shi Nan

AU - Zhai, Guang Yao

AU - Zhang, Yi Ming

AU - Lin, Yun Xiao

AU - Li, Xin Hao

AU - Chen, Jie Sheng

N1 - Funding Information: This work was supported by the National Natural Science Foundation of China (21722103, 21720102002, and 21673140) and the SJTU-MPI partner group. The authors thank the Shanghai Synchrotron Radiation Facility for providing beamtime (BL14W1). Publisher Copyright: © 2019 The Royal Society of Chemistry.

PY - 2019

Y1 - 2019

N2 - A nitrogen-thermal approach via the reaction between transition metal species and N dopants affords us the ability to optimize the tradeoff between the number of exposed transition metal/carbon (exemplified by cobalt in this work) boundaries and the most pronounced interfacial rectifying contact to achieve the highly efficient and selective hydrogenation and dehydrogenation of N-heterocycle compounds in a reversible manner.

AB - A nitrogen-thermal approach via the reaction between transition metal species and N dopants affords us the ability to optimize the tradeoff between the number of exposed transition metal/carbon (exemplified by cobalt in this work) boundaries and the most pronounced interfacial rectifying contact to achieve the highly efficient and selective hydrogenation and dehydrogenation of N-heterocycle compounds in a reversible manner.

UR - http://www.scopus.com/inward/record.url?scp=85072509602&partnerID=8YFLogxK

U2 - 10.1039/c9cc05114g

DO - 10.1039/c9cc05114g

M3 - Article

C2 - 31482882

AN - SCOPUS:85072509602

SN - 1359-7345

VL - 55

SP - 11394

EP - 11397

JO - CHEMICAL COMMUNICATIONS

JF - CHEMICAL COMMUNICATIONS

IS - 76

ER -

Nitrogen-thermal modification of the bifunctional interfaces of transition metal/carbon dyads for the reversible hydrogenation and dehydrogenation of heteroarenes

Abstract

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ASJC Scopus subject areas

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