Nitrogen atom transfer mediated by a new PN3P-pincer nickel core via a putative nitrido nickel intermediate

Changguang Yao; Xiufang Wang; Kuo-Wei Huang

doi:10.1039/c7cc09804a

Nitrogen atom transfer mediated by a new PN3P-pincer nickel core via a putative nitrido nickel intermediate

Changguang Yao, Xiufang Wang, Kuo-Wei Huang

Research output: Contribution to journal › Article › peer-review

18 Scopus citations

Abstract

A 2nd generation PN3P-pincer azido nickel complex (PN3P)Ni(N3) reacts with isocyanides to afford monosubstituted carbodiimides under irradiation, presumably via a transient nitrido intermediate. The resulting species can further generate unsymmetrical carboddimides and the PN3P nickel halide complex, accomplishing a synthetic cycle for a complete nitrogen atom transfer reaction.

Original language	English (US)
Pages (from-to)	3940-3943
Number of pages	4
Journal	Chemical Communications
Volume	54
Issue number	32
DOIs	https://doi.org/10.1039/c7cc09804a
State	Published - 2018

Bibliographical note

KAUST Repository Item: Exported on 2020-10-01
Acknowledgements: We acknowledge support from King Abdullah University of Science and Technology (KAUST).

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10.1039/c7cc09804a

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title = "Nitrogen atom transfer mediated by a new PN3P-pincer nickel core via a putative nitrido nickel intermediate",

abstract = "A 2nd generation PN3P-pincer azido nickel complex (PN3P)Ni(N3) reacts with isocyanides to afford monosubstituted carbodiimides under irradiation, presumably via a transient nitrido intermediate. The resulting species can further generate unsymmetrical carboddimides and the PN3P nickel halide complex, accomplishing a synthetic cycle for a complete nitrogen atom transfer reaction.",

author = "Changguang Yao and Xiufang Wang and Kuo-Wei Huang",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: We acknowledge support from King Abdullah University of Science and Technology (KAUST).",

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doi = "10.1039/c7cc09804a",

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AU - Yao, Changguang

AU - Wang, Xiufang

AU - Huang, Kuo-Wei

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: We acknowledge support from King Abdullah University of Science and Technology (KAUST).

PY - 2018

Y1 - 2018

N2 - A 2nd generation PN3P-pincer azido nickel complex (PN3P)Ni(N3) reacts with isocyanides to afford monosubstituted carbodiimides under irradiation, presumably via a transient nitrido intermediate. The resulting species can further generate unsymmetrical carboddimides and the PN3P nickel halide complex, accomplishing a synthetic cycle for a complete nitrogen atom transfer reaction.

AB - A 2nd generation PN3P-pincer azido nickel complex (PN3P)Ni(N3) reacts with isocyanides to afford monosubstituted carbodiimides under irradiation, presumably via a transient nitrido intermediate. The resulting species can further generate unsymmetrical carboddimides and the PN3P nickel halide complex, accomplishing a synthetic cycle for a complete nitrogen atom transfer reaction.

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UR - http://www.scopus.com/inward/record.url?scp=85045529897&partnerID=8YFLogxK

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DO - 10.1039/c7cc09804a

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SP - 3940

EP - 3943

JO - Chemical Communications

JF - Chemical Communications

IS - 32

ER -

Nitrogen atom transfer mediated by a new PN3P-pincer nickel core via a putative nitrido nickel intermediate

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CCDC 1811345: Experimental Crystal Structure Determination : (t-butylcyanamide)-{N,N'-(3,3,5-triethylpyridine-2,6(1H,3H)-diylidene)bis[P,P-di-t-butyl(phosphinous amidato)]}-nickel

CCDC 1811343: Experimental Crystal Structure Determination : azido-{N,N'-(3,3,5-triethylpyridine-2,6(1H,3H)-diylidene)bis[P,P-di-t-butyl(phosphinous amidato)]}-nickel

CCDC 1811347: Experimental Crystal Structure Determination : cyano-{N,N'-(3,3,5-triethylpyridine-2,6(1H,3H)-diylidene)bis[P,P-di-t-butyl(phosphinous amidato)]}-nickel

Cite this

Nitrogen atom transfer mediated by a new PN3P-pincer nickel core via a putative nitrido nickel intermediate

Abstract

Bibliographical note

Access to Document

Other files and links

Fingerprint

Datasets

CCDC 1811345: Experimental Crystal Structure Determination : (t-butylcyanamide)-{N,N'-(3,3,5-triethylpyridine-2,6(1H,3H)-diylidene)bis[P,P-di-t-butyl(phosphinous amidato)]}-nickel

CCDC 1811343: Experimental Crystal Structure Determination : azido-{N,N'-(3,3,5-triethylpyridine-2,6(1H,3H)-diylidene)bis[P,P-di-t-butyl(phosphinous amidato)]}-nickel

CCDC 1811347: Experimental Crystal Structure Determination : cyano-{N,N'-(3,3,5-triethylpyridine-2,6(1H,3H)-diylidene)bis[P,P-di-t-butyl(phosphinous amidato)]}-nickel

Cite this