Nickel-Catalyzed Synthesis of Silanes from Silyl Ketones

Watchara Srimontree, Waranya Lakornwong, Magnus Rueping

Research output: Contribution to journalArticlepeer-review

19 Scopus citations

Abstract

An unprecedented nickel-catalyzed decarbonylative silylation via CO extrusion intramolecular recombination fragment coupling of unstrained and nondirecting group-Assisted silyl ketones is described. The inexpensive and readily available catalyst performs under mild reaction conditions and enables the synthesis of structurally diverse arylsilanes, including heterocyclic and natural product derivatives.
Original languageEnglish (US)
Pages (from-to)9330-9333
Number of pages4
JournalOrganic Letters
Volume21
Issue number23
DOIs
StatePublished - Nov 8 2019

Bibliographical note

KAUST Repository Item: Exported on 2020-10-01
Acknowledgements: W.L. was supported by the Thailand Research Fund through the Royal Golden Jubilee Ph.D. Program for the one-year exchange fellowship to RWTH-Aachen University. We thank Tengfei Ji for performing the large scale experiment.

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