Nickel-Catalyzed Decarbonylative Silylation, Borylation, and Amination of Arylamides via a Deamidative Reaction Pathway

Shao Chi Lee; Lin Guo; Huifeng Yue; Hsuan Hung Liao; Magnus Rueping

doi:10.1055/s-0036-1591495

Nickel-Catalyzed Decarbonylative Silylation, Borylation, and Amination of Arylamides via a Deamidative Reaction Pathway

Shao Chi Lee, Lin Guo, Huifeng Yue, Hsuan Hung Liao, Magnus Rueping^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

54 Scopus citations

Abstract

A nickel-catalyzed decarbonylative silylation, borylation, and amination of amides has been developed. This new methodology allows the direct interconversion of amides to arylsilanes, arylboronates, and arylamines and enables a facile route for carbon-heteroatom bond formations in a straightforward and mild fashion.

Original language	English (US)
Pages (from-to)	2594-2598
Number of pages	5
Journal	Synlett
Volume	28
Issue number	19
DOIs	https://doi.org/10.1055/s-0036-1591495
State	Published - Dec 1 2017

Bibliographical note

Publisher Copyright:
© Georg Thieme Verlag Stuttgart, New York.

Keywords

amination
borylation
decarbonylation
nickel catalysis
silylation

ASJC Scopus subject areas

Organic Chemistry

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10.1055/s-0036-1591495

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AU - Guo, Lin

AU - Yue, Huifeng

AU - Liao, Hsuan Hung

AU - Rueping, Magnus

N1 - Publisher Copyright: © Georg Thieme Verlag Stuttgart, New York.

PY - 2017/12/1

Y1 - 2017/12/1

N2 - A nickel-catalyzed decarbonylative silylation, borylation, and amination of amides has been developed. This new methodology allows the direct interconversion of amides to arylsilanes, arylboronates, and arylamines and enables a facile route for carbon-heteroatom bond formations in a straightforward and mild fashion.

AB - A nickel-catalyzed decarbonylative silylation, borylation, and amination of amides has been developed. This new methodology allows the direct interconversion of amides to arylsilanes, arylboronates, and arylamines and enables a facile route for carbon-heteroatom bond formations in a straightforward and mild fashion.

KW - amination

KW - borylation

KW - decarbonylation

KW - nickel catalysis

KW - silylation

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ER -

Nickel-Catalyzed Decarbonylative Silylation, Borylation, and Amination of Arylamides via a Deamidative Reaction Pathway

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

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