New approach for understanding the mechanism of butadiene and butenol reactions with Pd(TPPTS) 3 catalyst in water

Emile Kuntz; Jean Marie Basset; Denis Bouchu; Gregory Godard; Frédéric Lefebvre; Nicolas Legagneux; Christine Lucas; Daniel Michelet

doi:10.1021/om9009125

New approach for understanding the mechanism of butadiene and butenol reactions with Pd(TPPTS) ₃ catalyst in water

Emile Kuntz^*, Jean Marie Basset, Denis Bouchu, Gregory Godard, Frédéric Lefebvre, Nicolas Legagneux, Christine Lucas, Daniel Michelet

^*Corresponding author for this work

Physical Sciences and Engineering

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

The complex Pd(TPPTS) ₃ reacts in water at room temperature with butenols (ionization) or butadiene (protonation) to produce two isomeric hydrosoluble η ³-allylic palladium complexes ([Pd(syn-C ₄)(TPPTS) ₂] ⁺ and [Pd(anti-C ₄)(TPPTS) ₂] ⁺) and three isomers of butenylphosphonium salts of TPPTS. The pH has a great influence on the reaction rates and on the stability of the products.

Original language	English (US)
Pages (from-to)	523-526
Number of pages	4
Journal	Organometallics
Volume	29
Issue number	3
DOIs	https://doi.org/10.1021/om9009125
State	Published - Feb 8 2010

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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title = "New approach for understanding the mechanism of butadiene and butenol reactions with Pd(TPPTS) 3 catalyst in water",

abstract = "The complex Pd(TPPTS) 3 reacts in water at room temperature with butenols (ionization) or butadiene (protonation) to produce two isomeric hydrosoluble η 3-allylic palladium complexes ([Pd(syn-C 4)(TPPTS) 2] + and [Pd(anti-C 4)(TPPTS) 2] +) and three isomers of butenylphosphonium salts of TPPTS. The pH has a great influence on the reaction rates and on the stability of the products.",

author = "Emile Kuntz and Basset, {Jean Marie} and Denis Bouchu and Gregory Godard and Fr{\'e}d{\'e}ric Lefebvre and Nicolas Legagneux and Christine Lucas and Daniel Michelet",

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T1 - New approach for understanding the mechanism of butadiene and butenol reactions with Pd(TPPTS) 3 catalyst in water

AU - Kuntz, Emile

AU - Basset, Jean Marie

AU - Bouchu, Denis

AU - Godard, Gregory

AU - Lefebvre, Frédéric

AU - Legagneux, Nicolas

AU - Lucas, Christine

AU - Michelet, Daniel

PY - 2010/2/8

Y1 - 2010/2/8

N2 - The complex Pd(TPPTS) 3 reacts in water at room temperature with butenols (ionization) or butadiene (protonation) to produce two isomeric hydrosoluble η 3-allylic palladium complexes ([Pd(syn-C 4)(TPPTS) 2] + and [Pd(anti-C 4)(TPPTS) 2] +) and three isomers of butenylphosphonium salts of TPPTS. The pH has a great influence on the reaction rates and on the stability of the products.

AB - The complex Pd(TPPTS) 3 reacts in water at room temperature with butenols (ionization) or butadiene (protonation) to produce two isomeric hydrosoluble η 3-allylic palladium complexes ([Pd(syn-C 4)(TPPTS) 2] + and [Pd(anti-C 4)(TPPTS) 2] +) and three isomers of butenylphosphonium salts of TPPTS. The pH has a great influence on the reaction rates and on the stability of the products.

UR - http://www.scopus.com/inward/record.url?scp=76149098216&partnerID=8YFLogxK

U2 - 10.1021/om9009125

DO - 10.1021/om9009125

M3 - Article

AN - SCOPUS:76149098216

SN - 0276-7333

VL - 29

SP - 523

EP - 526

JO - Organometallics

JF - Organometallics

IS - 3

ER -

New approach for understanding the mechanism of butadiene and butenol reactions with Pd(TPPTS) ₃ catalyst in water

Abstract

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