Natural phosphate-supported palladium: A highly efficient and recyclable catalyst for the suzuki-miyaura coupling under microwave irradiation

Ayoub Hassine; Mohamed Bouhrara; Said Sebti; Abderrahim Solhy; Remi Mahfouz; Denis Luart; Christophe Lene; Aziz Fihri

doi:10.2174/1385272819666141117234222

Natural phosphate-supported palladium: A highly efficient and recyclable catalyst for the suzuki-miyaura coupling under microwave irradiation

Ayoub Hassine, Mohamed Bouhrara, Said Sebti, Abderrahim Solhy, Remi Mahfouz, Denis Luart, Christophe Lene, Aziz Fihri

Research output: Contribution to journal › Article › peer-review

19 Scopus citations

Abstract

This report explores Suzuki-Miyaura coupling under microwave irradiation, using a new generation of catalyst that is based on natural phosphate (NP) impregnated by palladium. This catalyst was prepared by the treatment of natural phosphate with bis(benzonitrile)palladium(II) chloride in acetone at room temperature. The catalyst displayed high catalytic activity for the Suzuki-Miyaura coupling of aryl bromides and chlorides with aryl boronic acids in pure water and with the use of microwave irradiation. The low-cost and availability of the solid support, mild reaction conditions, high yields of desired products, recyclability of the catalyst and short reaction times are the notable features of these methods.

Original language	English (US)
Pages (from-to)	3141-3148
Number of pages	8
Journal	Current Organic Chemistry
Volume	18
Issue number	24
DOIs	https://doi.org/10.2174/1385272819666141117234222
State	Published - Jan 19 2015

Bibliographical note

KAUST Repository Item: Exported on 2020-10-01
Acknowledgements: We thank G. Santini for his support of this work and the Region Picardie for their financial support. The financial assistance of the Office Cherifien des Phosphates in the Moroccan Kingdom (OCP Group) towards this research is hereby acknowledged. This work was supported also by grant from the OCP Foundation.

ASJC Scopus subject areas

Organic Chemistry

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10.2174/1385272819666141117234222

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title = "Natural phosphate-supported palladium: A highly efficient and recyclable catalyst for the suzuki-miyaura coupling under microwave irradiation",

abstract = "This report explores Suzuki-Miyaura coupling under microwave irradiation, using a new generation of catalyst that is based on natural phosphate (NP) impregnated by palladium. This catalyst was prepared by the treatment of natural phosphate with bis(benzonitrile)palladium(II) chloride in acetone at room temperature. The catalyst displayed high catalytic activity for the Suzuki-Miyaura coupling of aryl bromides and chlorides with aryl boronic acids in pure water and with the use of microwave irradiation. The low-cost and availability of the solid support, mild reaction conditions, high yields of desired products, recyclability of the catalyst and short reaction times are the notable features of these methods.",

author = "Ayoub Hassine and Mohamed Bouhrara and Said Sebti and Abderrahim Solhy and Remi Mahfouz and Denis Luart and Christophe Lene and Aziz Fihri",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: We thank G. Santini for his support of this work and the Region Picardie for their financial support. The financial assistance of the Office Cherifien des Phosphates in the Moroccan Kingdom (OCP Group) towards this research is hereby acknowledged. This work was supported also by grant from the OCP Foundation.",

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T1 - Natural phosphate-supported palladium: A highly efficient and recyclable catalyst for the suzuki-miyaura coupling under microwave irradiation

AU - Hassine, Ayoub

AU - Bouhrara, Mohamed

AU - Sebti, Said

AU - Solhy, Abderrahim

AU - Mahfouz, Remi

AU - Luart, Denis

AU - Lene, Christophe

AU - Fihri, Aziz

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: We thank G. Santini for his support of this work and the Region Picardie for their financial support. The financial assistance of the Office Cherifien des Phosphates in the Moroccan Kingdom (OCP Group) towards this research is hereby acknowledged. This work was supported also by grant from the OCP Foundation.

PY - 2015/1/19

Y1 - 2015/1/19

N2 - This report explores Suzuki-Miyaura coupling under microwave irradiation, using a new generation of catalyst that is based on natural phosphate (NP) impregnated by palladium. This catalyst was prepared by the treatment of natural phosphate with bis(benzonitrile)palladium(II) chloride in acetone at room temperature. The catalyst displayed high catalytic activity for the Suzuki-Miyaura coupling of aryl bromides and chlorides with aryl boronic acids in pure water and with the use of microwave irradiation. The low-cost and availability of the solid support, mild reaction conditions, high yields of desired products, recyclability of the catalyst and short reaction times are the notable features of these methods.

AB - This report explores Suzuki-Miyaura coupling under microwave irradiation, using a new generation of catalyst that is based on natural phosphate (NP) impregnated by palladium. This catalyst was prepared by the treatment of natural phosphate with bis(benzonitrile)palladium(II) chloride in acetone at room temperature. The catalyst displayed high catalytic activity for the Suzuki-Miyaura coupling of aryl bromides and chlorides with aryl boronic acids in pure water and with the use of microwave irradiation. The low-cost and availability of the solid support, mild reaction conditions, high yields of desired products, recyclability of the catalyst and short reaction times are the notable features of these methods.

UR - http://hdl.handle.net/10754/564014

UR - http://www.eurekaselect.com/openurl/content.php?genre=article&issn=1385-2728&volume=18&issue=24&spage=3141

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DO - 10.2174/1385272819666141117234222

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VL - 18

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JO - Current Organic Chemistry

JF - Current Organic Chemistry

IS - 24

ER -

Natural phosphate-supported palladium: A highly efficient and recyclable catalyst for the suzuki-miyaura coupling under microwave irradiation

Abstract

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