n-Type Organic Electrochemical Transistors with High Transconductance and Stability

Yazhou Wang; Genming Zhu; Erica Zeglio; Tania Cecilia Hidalgo Castillo; Sheik Haseena; Mahesh Kumar Ravva; Shengyu Cong; Junxin Chen; Liuyuan Lan; Zhengke Li; Anna Herland; Iain Mcculloch; Sahika Inal; Wan Yue

doi:10.1021/acs.chemmater.2c02447

n-Type Organic Electrochemical Transistors with High Transconductance and Stability

Yazhou Wang, Genming Zhu, Erica Zeglio, Tania Cecilia Hidalgo Castillo, Sheik Haseena, Mahesh Kumar Ravva, Shengyu Cong, Junxin Chen, Liuyuan Lan, Zhengke Li, Anna Herland, Iain Mcculloch, Sahika Inal, Wan Yue

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

An n-type conjugated polymer based on diazaisoindigo (AIID) and fluorinated thiophene units is introduced. Combining the strong electron-accepting properties of AIID with backbone fluorination produced gAIID-2FT, leading to organic electrochemical transistors (OECTs) with normalized values of 4.09 F cm-1 V-1 s-1 and a normalized transconductance (gm,norm) of 0.94 S cm-1. The resulting OECTs exhibit exceptional operational stability and long shelf-life in ambient conditions, preserving 100% of the original maximum drain current after over 3 h of continuous operation and 28 days of storage in the air. Our work highlights the advantages of integrating strong electron acceptors with donor fluorination to boost the performance and stability of n-type OECTs.

Original language	English (US)
Journal	Chemistry of Materials
DOIs	https://doi.org/10.1021/acs.chemmater.2c02447
State	Accepted/In press - 2022

Bibliographical note

Funding Information:
The authors thank the National Natural Science Foundation of China (Grant No. 21875291) and the Guangdong Provincial Foundation for Basic and Applied Basic Research (Grant No. 2021A1515110261) for the financial support. E.Z. and A.H. gratefully acknowledge the Knut and Alice Wallenberg Foundation (Grant No. KAW2015.0178), the Swedish Research Council (Grant No. 2018-03483 and International Postdoc Grant No. 2017-06381), and the European Union’s Horizon 2020 research and innovation program under the Marie Sklodowska-Curie grant agreement “BioResORGEL” (Program No. 101025599).

Publisher Copyright:
© 2023 American Chemical Society.

ASJC Scopus subject areas

General Chemistry
General Chemical Engineering
Materials Chemistry

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10.1021/acs.chemmater.2c02447

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title = "n-Type Organic Electrochemical Transistors with High Transconductance and Stability",

abstract = "An n-type conjugated polymer based on diazaisoindigo (AIID) and fluorinated thiophene units is introduced. Combining the strong electron-accepting properties of AIID with backbone fluorination produced gAIID-2FT, leading to organic electrochemical transistors (OECTs) with normalized values of 4.09 F cm-1 V-1 s-1 and a normalized transconductance (gm,norm) of 0.94 S cm-1. The resulting OECTs exhibit exceptional operational stability and long shelf-life in ambient conditions, preserving 100% of the original maximum drain current after over 3 h of continuous operation and 28 days of storage in the air. Our work highlights the advantages of integrating strong electron acceptors with donor fluorination to boost the performance and stability of n-type OECTs.",

author = "Yazhou Wang and Genming Zhu and Erica Zeglio and Castillo, {Tania Cecilia Hidalgo} and Sheik Haseena and Ravva, {Mahesh Kumar} and Shengyu Cong and Junxin Chen and Liuyuan Lan and Zhengke Li and Anna Herland and Iain Mcculloch and Sahika Inal and Wan Yue",

note = "Funding Information: The authors thank the National Natural Science Foundation of China (Grant No. 21875291) and the Guangdong Provincial Foundation for Basic and Applied Basic Research (Grant No. 2021A1515110261) for the financial support. E.Z. and A.H. gratefully acknowledge the Knut and Alice Wallenberg Foundation (Grant No. KAW2015.0178), the Swedish Research Council (Grant No. 2018-03483 and International Postdoc Grant No. 2017-06381), and the European Union{\textquoteright}s Horizon 2020 research and innovation program under the Marie Sklodowska-Curie grant agreement “BioResORGEL” (Program No. 101025599). Publisher Copyright: {\textcopyright} 2023 American Chemical Society.",

year = "2022",

doi = "10.1021/acs.chemmater.2c02447",

language = "English (US)",

journal = "Chemistry of Materials",

issn = "0897-4756",

publisher = "AMER CHEMICAL SOC",

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T1 - n-Type Organic Electrochemical Transistors with High Transconductance and Stability

AU - Wang, Yazhou

AU - Zhu, Genming

AU - Zeglio, Erica

AU - Castillo, Tania Cecilia Hidalgo

AU - Haseena, Sheik

AU - Ravva, Mahesh Kumar

AU - Cong, Shengyu

AU - Chen, Junxin

AU - Lan, Liuyuan

AU - Li, Zhengke

AU - Herland, Anna

AU - Mcculloch, Iain

AU - Inal, Sahika

AU - Yue, Wan

N1 - Funding Information: The authors thank the National Natural Science Foundation of China (Grant No. 21875291) and the Guangdong Provincial Foundation for Basic and Applied Basic Research (Grant No. 2021A1515110261) for the financial support. E.Z. and A.H. gratefully acknowledge the Knut and Alice Wallenberg Foundation (Grant No. KAW2015.0178), the Swedish Research Council (Grant No. 2018-03483 and International Postdoc Grant No. 2017-06381), and the European Union’s Horizon 2020 research and innovation program under the Marie Sklodowska-Curie grant agreement “BioResORGEL” (Program No. 101025599). Publisher Copyright: © 2023 American Chemical Society.

PY - 2022

Y1 - 2022

N2 - An n-type conjugated polymer based on diazaisoindigo (AIID) and fluorinated thiophene units is introduced. Combining the strong electron-accepting properties of AIID with backbone fluorination produced gAIID-2FT, leading to organic electrochemical transistors (OECTs) with normalized values of 4.09 F cm-1 V-1 s-1 and a normalized transconductance (gm,norm) of 0.94 S cm-1. The resulting OECTs exhibit exceptional operational stability and long shelf-life in ambient conditions, preserving 100% of the original maximum drain current after over 3 h of continuous operation and 28 days of storage in the air. Our work highlights the advantages of integrating strong electron acceptors with donor fluorination to boost the performance and stability of n-type OECTs.

AB - An n-type conjugated polymer based on diazaisoindigo (AIID) and fluorinated thiophene units is introduced. Combining the strong electron-accepting properties of AIID with backbone fluorination produced gAIID-2FT, leading to organic electrochemical transistors (OECTs) with normalized values of 4.09 F cm-1 V-1 s-1 and a normalized transconductance (gm,norm) of 0.94 S cm-1. The resulting OECTs exhibit exceptional operational stability and long shelf-life in ambient conditions, preserving 100% of the original maximum drain current after over 3 h of continuous operation and 28 days of storage in the air. Our work highlights the advantages of integrating strong electron acceptors with donor fluorination to boost the performance and stability of n-type OECTs.

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U2 - 10.1021/acs.chemmater.2c02447

DO - 10.1021/acs.chemmater.2c02447

M3 - Article

AN - SCOPUS:85146133468

SN - 0897-4756

JO - Chemistry of Materials

JF - Chemistry of Materials

ER -

n-Type Organic Electrochemical Transistors with High Transconductance and Stability

Abstract

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