N-Heterocyclic carbene-catalysed synthesis of polyurethanes

Olivier Coutelier; Mohammad El Ezzi; Mathias Destarac; Fabien Bonnette; Tsuyoshi Kato; Antoine Baceiredo; Gopakumar Sivasankarapillai; Yves Gnanou; Daniel Taton

doi:10.1039/c2py00477a

N-Heterocyclic carbene-catalysed synthesis of polyurethanes

Olivier Coutelier, Mohammad El Ezzi, Mathias Destarac^*, Fabien Bonnette, Tsuyoshi Kato, Antoine Baceiredo, Gopakumar Sivasankarapillai, Yves Gnanou, Daniel Taton

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

43 Scopus citations

Abstract

A free N-heterocyclic carbene has been efficiently used for the organocatalysed step-growth polymerisation between aliphatic diisocyanates and diols. Both the nature of the diisocyanate monomer and the order of addition of reactants are critical parameters for the successful synthesis of soluble linear polyurethanes.

Original language	English (US)
Pages (from-to)	605-608
Number of pages	4
Journal	POLYMER CHEMISTRY
Volume	3
Issue number	3
DOIs	https://doi.org/10.1039/c2py00477a
State	Published - Mar 2012
Externally published	Yes

ASJC Scopus subject areas

Bioengineering
Biochemistry
Polymers and Plastics
Organic Chemistry

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10.1039/c2py00477a

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title = "N-Heterocyclic carbene-catalysed synthesis of polyurethanes",

abstract = "A free N-heterocyclic carbene has been efficiently used for the organocatalysed step-growth polymerisation between aliphatic diisocyanates and diols. Both the nature of the diisocyanate monomer and the order of addition of reactants are critical parameters for the successful synthesis of soluble linear polyurethanes.",

author = "Olivier Coutelier and {El Ezzi}, Mohammad and Mathias Destarac and Fabien Bonnette and Tsuyoshi Kato and Antoine Baceiredo and Gopakumar Sivasankarapillai and Yves Gnanou and Daniel Taton",

year = "2012",

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doi = "10.1039/c2py00477a",

language = "English (US)",

volume = "3",

pages = "605--608",

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issn = "1759-9954",

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TY - JOUR

T1 - N-Heterocyclic carbene-catalysed synthesis of polyurethanes

AU - Coutelier, Olivier

AU - El Ezzi, Mohammad

AU - Destarac, Mathias

AU - Bonnette, Fabien

AU - Kato, Tsuyoshi

AU - Baceiredo, Antoine

AU - Sivasankarapillai, Gopakumar

AU - Gnanou, Yves

AU - Taton, Daniel

PY - 2012/3

Y1 - 2012/3

N2 - A free N-heterocyclic carbene has been efficiently used for the organocatalysed step-growth polymerisation between aliphatic diisocyanates and diols. Both the nature of the diisocyanate monomer and the order of addition of reactants are critical parameters for the successful synthesis of soluble linear polyurethanes.

AB - A free N-heterocyclic carbene has been efficiently used for the organocatalysed step-growth polymerisation between aliphatic diisocyanates and diols. Both the nature of the diisocyanate monomer and the order of addition of reactants are critical parameters for the successful synthesis of soluble linear polyurethanes.

UR - http://www.scopus.com/inward/record.url?scp=84857312176&partnerID=8YFLogxK

U2 - 10.1039/c2py00477a

DO - 10.1039/c2py00477a

M3 - Article

AN - SCOPUS:84857312176

SN - 1759-9954

VL - 3

SP - 605

EP - 608

JO - POLYMER CHEMISTRY

JF - POLYMER CHEMISTRY

IS - 3

ER -

N-Heterocyclic carbene-catalysed synthesis of polyurethanes

Abstract

ASJC Scopus subject areas

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