Morphology and deformation mechanisms and tensile properties of tetrafunctional multigraft copolymers

Yongxin Duan, Mahendra Thunga, Ralf Schlegel, Konrad Schneider, Erik Rettler, Roland Weidisch*, Heinz W. Siesler, Manfred Stamm, Jimmy W. Mays, Nikos Hadjichristidis

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

52 Scopus citations


Morphology and deformation mechanisms and tensile properties of tetrafunctional multi-graft (MG) polystrene-g-polyisoprene (PS-g-PI) copolymers were investigated dependent on PS volume fraction and number of branch points. The combination of various methods such as TEM, real time synchrotron SAXS, rheo-optical FTIR, and tensile tests provides comprehensive information at different dimension levels. TEM and SAXS studies revealed that the number of branch points has no obvious influence on the microphase-separated morphology of tetrafunction MG copolymers with 16 wt % PS. But for tetrafunctional MG copolymers with 25 wt % PS, the size and integrity of PS microdomains decrease with increasing number of branch point. The deformation mechanisms of MG copolymers are highly related to the morphology. Dependent on the microphase-separated morphology and integrity of the PS phase, the strain-induced orientation of the PS phase is at different size scales. Polarized FT-IR spectra analysis reveals that, for all investigated MG copolymers, the PI phase shows strain-induced orientation along SD at molecular scale. The proportion of the PI block effectively bridging PS domains controls the tensile properties of the MG copolymers at high strain, while the stress - strain behavior in the low-mediate strain region is controlled by the continuity of PS microdomains. The special molecular architecture, which leads to the higher effective functionality of PS domains and the higher possibility for an individual PI backbone being tethered with a large number of PS domains, is proposed to be the origin of the superelasticity for MG copolymers.

Original languageEnglish (US)
Pages (from-to)4155-4164
Number of pages10
Issue number12
StatePublished - Jun 23 2009
Externally publishedYes

ASJC Scopus subject areas

  • Organic Chemistry
  • Polymers and Plastics
  • Inorganic Chemistry
  • Materials Chemistry


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