Molecular Weight Dependence of Hydrodynamic and Thermodynamic Properties for Well-Defined Linear Polymers in Solution

L. J. Fetters; N. Hadjichristidis; J. S. Lindner; J. W. Mays

doi:10.1063/1.555949

Molecular Weight Dependence of Hydrodynamic and Thermodynamic Properties for Well-Defined Linear Polymers in Solution

L. J. Fetters, N. Hadjichristidis, J. S. Lindner, J. W. Mays

Research output: Contribution to journal › Article › peer-review

241 Scopus citations

Abstract

Data on hydrodynamic and thermodynamic properties of several well-defined, linear flexible polymer chains in thermodynamically good solvents and theta solvents are tabulated and critically evaluated. The polymers considered are 1,4-polybutadiene, 1,4-polyisoprene, polyisobutylene, polystyrene, and poly(α-methylstyrene). Extensive data, obtained as a function of molecular weight, are evaluated for the intrinsic viscosity, radius of gyration, hydrodynamic radius, and second virial coefficient. The resulting power law relationships between the measured properties and polymer molecular weight are reported.

Original language	English (US)
Pages (from-to)	619-640
Number of pages	22
Journal	Journal of Physical and Chemical Reference Data
Volume	23
Issue number	4
DOIs	https://doi.org/10.1063/1.555949
State	Published - Jul 1994
Externally published	Yes

Keywords

0870
0890
1160
1170
BUTADIENE
DATA
HYDRODYNAMICS
HYDRODYNAMICS
LINEAR CHAINS
METHYL COMPOUNDS
MOLECULAR WEIGHT
ORGANIC POLYMERS
POLYISOPRENE
POLYSTYRENE
SOLUTIONS
SOLVENTS
STYRENE
THERMODYNAMIC PROPERTIES
VIRIAL THEOREM
VISCOSITY

ASJC Scopus subject areas

General Chemistry
General Physics and Astronomy
Physical and Theoretical Chemistry

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10.1063/1.555949

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title = "Molecular Weight Dependence of Hydrodynamic and Thermodynamic Properties for Well-Defined Linear Polymers in Solution",

abstract = "Data on hydrodynamic and thermodynamic properties of several well-defined, linear flexible polymer chains in thermodynamically good solvents and theta solvents are tabulated and critically evaluated. The polymers considered are 1,4-polybutadiene, 1,4-polyisoprene, polyisobutylene, polystyrene, and poly(α-methylstyrene). Extensive data, obtained as a function of molecular weight, are evaluated for the intrinsic viscosity, radius of gyration, hydrodynamic radius, and second virial coefficient. The resulting power law relationships between the measured properties and polymer molecular weight are reported.",

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author = "Fetters, {L. J.} and N. Hadjichristidis and Lindner, {J. S.} and Mays, {J. W.}",

year = "1994",

month = jul,

doi = "10.1063/1.555949",

language = "English (US)",

volume = "23",

pages = "619--640",

journal = "Journal of Physical and Chemical Reference Data",

issn = "0047-2689",

publisher = "American Institute of Physics",

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AU - Fetters, L. J.

AU - Hadjichristidis, N.

AU - Lindner, J. S.

AU - Mays, J. W.

PY - 1994/7

Y1 - 1994/7

N2 - Data on hydrodynamic and thermodynamic properties of several well-defined, linear flexible polymer chains in thermodynamically good solvents and theta solvents are tabulated and critically evaluated. The polymers considered are 1,4-polybutadiene, 1,4-polyisoprene, polyisobutylene, polystyrene, and poly(α-methylstyrene). Extensive data, obtained as a function of molecular weight, are evaluated for the intrinsic viscosity, radius of gyration, hydrodynamic radius, and second virial coefficient. The resulting power law relationships between the measured properties and polymer molecular weight are reported.

AB - Data on hydrodynamic and thermodynamic properties of several well-defined, linear flexible polymer chains in thermodynamically good solvents and theta solvents are tabulated and critically evaluated. The polymers considered are 1,4-polybutadiene, 1,4-polyisoprene, polyisobutylene, polystyrene, and poly(α-methylstyrene). Extensive data, obtained as a function of molecular weight, are evaluated for the intrinsic viscosity, radius of gyration, hydrodynamic radius, and second virial coefficient. The resulting power law relationships between the measured properties and polymer molecular weight are reported.

KW - 0870

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KW - 1160

KW - 1170

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KW - DATA

KW - HYDRODYNAMICS

KW - LINEAR CHAINS

KW - METHYL COMPOUNDS

KW - MOLECULAR WEIGHT

KW - ORGANIC POLYMERS

KW - POLYISOPRENE

KW - POLYSTYRENE

KW - SOLUTIONS

KW - SOLVENTS

KW - STYRENE

KW - THERMODYNAMIC PROPERTIES

KW - VIRIAL THEOREM

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JO - Journal of Physical and Chemical Reference Data

JF - Journal of Physical and Chemical Reference Data

IS - 4

ER -

Molecular Weight Dependence of Hydrodynamic and Thermodynamic Properties for Well-Defined Linear Polymers in Solution

Abstract

Keywords

ASJC Scopus subject areas

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