Molecular adsorption induces the transformation of rhombohedral- to Bernal-stacking order in trilayer graphene

Wenjing Zhang, Jiaxu Yan, Chang Hsiao Chen, Liu Lei, Jer Lai Kuo, Zexiang Shen*, Lain Jong Li

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

32 Scopus citations

Abstract

The Bernal (ABA)-stacked graphene trilayer is presumed to be thermodynamically more stable than the rhombohedral (ABC) counterpart. However, the thermal transformation from ABC to ABA domains does not occur at a temperature lower than 1,000 °C. Here we report that ABC-stacked trilayers are transformed to ABA-stacked layers after an organic molecule triazine is evaporated onto graphene surfaces at 150 °C. The transformation is found to always initiate at the ABA-ABC domain boundaries. Simulations based on density function theory considering the van der Waals interaction suggest that after triazine decoration the energy difference between ABA and ABC domains is larger, providing a driving force for stacking transformation. The molecular dynamics simulation results further suggest that the triazine decoration on the wrinkles at the ABC-ABA domain boundary activates the wrinkle sliding toward the ABC domains, leading to the stacking transformation from ABC to ABA.

Original languageEnglish (US)
Article number2074
JournalNature Communications
Volume4
DOIs
StatePublished - Jun 25 2013
Externally publishedYes

Bibliographical note

Publisher Copyright:
© 2013 Macmillan Publishers Limited. All rights reserved.

ASJC Scopus subject areas

  • General Chemistry
  • General Biochemistry, Genetics and Molecular Biology
  • General Physics and Astronomy

Fingerprint

Dive into the research topics of 'Molecular adsorption induces the transformation of rhombohedral- to Bernal-stacking order in trilayer graphene'. Together they form a unique fingerprint.

Cite this