Abstract
Lithium-sulfur (Li-S) batteries have garnered a lot of attention in the realm of electrochemical energy storage owing to their high energy and low cost. However, the serious polysulfide shuttle effect of the sulfur cathode poses a critical challenge for the development of Li-S batteries with elevated sulfur loadings. In addition, the poor robustness of traditional blade-casting cathodes greatly impedes the practical applications of flexible Li-S cells that display high areal capacity. To address these concerns, we report herein a freestanding hybrid sulfur host via in situ crafting of flexible carbon cloth (CC), vertically grown graphene nanoflakes over CC (G/CC) and metal-organic-framework derived CoP anchored on vertical graphene (CoP@G/CC). The thus-derived sulfur cathodes (CoP@G/CC-S) with a typical sulfur loading of 2 mg cm-2 exhibit outstanding electrochemical performances, including excellent rate capability (930.1 mA h g-1 at 3.0C) and impressive cycling stability (0.03% capacity decay per cycle after 500 cycles at 2.0C). A high areal capacity of 8.81 mA h cm-2 at 0.05C can also be obtained even at an elevated sulfur loading of 10.83 mg cm-2. Furthermore, flexible pouch cells based on the self-supported CoP@G/CC-S showcase favorable rate and cycling performances with high mechanical robustness.
Original language | English (US) |
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Pages (from-to) | 3027-3034 |
Number of pages | 8 |
Journal | Journal of Materials Chemistry A |
Volume | 8 |
Issue number | 6 |
DOIs | |
State | Published - Jan 14 2020 |
Bibliographical note
KAUST Repository Item: Exported on 2020-10-01Acknowledgements: PSV would like to express his sincere gratitude to the College management for their financial support to develop a nanomaterials laboratory.