Modulating the packing of [Cu24(isophthalate)24] cuboctahedra in a triazole-containing metal–organic polyhedral framework

Yong Yan; Mikhail Suyetin; Elena Bichoutskaia; Alexander J. Blake; David R. Allan; Sarah A. Barnett; Martin Schröder

doi:10.1039/c3sc21769h

Modulating the packing of [Cu₂₄(isophthalate)₂₄] cuboctahedra in a triazole-containing metal–organic polyhedral framework

Yong Yan, Mikhail Suyetin, Elena Bichoutskaia, Alexander J. Blake, David R. Allan, Sarah A. Barnett, Martin Schröder^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

115 Scopus citations

Abstract

The highly porous (3,24)-connected framework NOTT-122 incorporates a C₃-symmetric angularly connected isophthalate linker containing 1,2,3-triazole rings and shows body-centered tetragonal packing of [Cu₂₄(isophthalate)₂₄] cuboctahedra. This unique packing, coupled with the high density of free N-donor sites, is responsible for the simultaneous high H₂, CH₄ and CO₂ adsorption capacities in desolvated NOTT-122a.

Original language	English (US)
Pages (from-to)	1731-1736
Number of pages	6
Journal	Chemical Science
Volume	4
Issue number	4
DOIs	https://doi.org/10.1039/c3sc21769h
State	Published - Mar 4 2013
Externally published	Yes

ASJC Scopus subject areas

General Chemistry

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title = "Modulating the packing of [Cu24(isophthalate)24] cuboctahedra in a triazole-containing metal–organic polyhedral framework",

abstract = "The highly porous (3,24)-connected framework NOTT-122 incorporates a C3-symmetric angularly connected isophthalate linker containing 1,2,3-triazole rings and shows body-centered tetragonal packing of [Cu24(isophthalate)24] cuboctahedra. This unique packing, coupled with the high density of free N-donor sites, is responsible for the simultaneous high H2, CH4 and CO2 adsorption capacities in desolvated NOTT-122a.",

author = "Yong Yan and Mikhail Suyetin and Elena Bichoutskaia and Blake, {Alexander J.} and Allan, {David R.} and Barnett, {Sarah A.} and Martin Schr{\"o}der",

year = "2013",

month = mar,

day = "4",

doi = "10.1039/c3sc21769h",

language = "English (US)",

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journal = "Chemical Science",

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T1 - Modulating the packing of [Cu24(isophthalate)24] cuboctahedra in a triazole-containing metal–organic polyhedral framework

AU - Yan, Yong

AU - Suyetin, Mikhail

AU - Bichoutskaia, Elena

AU - Blake, Alexander J.

AU - Allan, David R.

AU - Barnett, Sarah A.

AU - Schröder, Martin

PY - 2013/3/4

Y1 - 2013/3/4

N2 - The highly porous (3,24)-connected framework NOTT-122 incorporates a C3-symmetric angularly connected isophthalate linker containing 1,2,3-triazole rings and shows body-centered tetragonal packing of [Cu24(isophthalate)24] cuboctahedra. This unique packing, coupled with the high density of free N-donor sites, is responsible for the simultaneous high H2, CH4 and CO2 adsorption capacities in desolvated NOTT-122a.

AB - The highly porous (3,24)-connected framework NOTT-122 incorporates a C3-symmetric angularly connected isophthalate linker containing 1,2,3-triazole rings and shows body-centered tetragonal packing of [Cu24(isophthalate)24] cuboctahedra. This unique packing, coupled with the high density of free N-donor sites, is responsible for the simultaneous high H2, CH4 and CO2 adsorption capacities in desolvated NOTT-122a.

UR - http://www.scopus.com/inward/record.url?scp=84874614074&partnerID=8YFLogxK

U2 - 10.1039/c3sc21769h

DO - 10.1039/c3sc21769h

M3 - Article

AN - SCOPUS:84874614074

SN - 2041-6520

VL - 4

SP - 1731

EP - 1736

JO - Chemical Science

JF - Chemical Science

IS - 4

ER -

Modulating the packing of [Cu₂₄(isophthalate)₂₄] cuboctahedra in a triazole-containing metal–organic polyhedral framework

Abstract

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