Modification of the surface properties of indium tin oxide with benzylphosphonic acids: A joint experimental and theoretical study

Peter J. Hotchkiss; Hong Li; Pavel B. Paramonov; Sergio A. Paniagua; Simon C. Jones; Neal R. Armstrong; Jean Luc Brédas; Seth R. Marder

doi:10.1002/adma.200900502

Modification of the surface properties of indium tin oxide with benzylphosphonic acids: A joint experimental and theoretical study

Peter J. Hotchkiss, Hong Li, Pavel B. Paramonov, Sergio A. Paniagua, Simon C. Jones, Neal R. Armstrong, Jean Luc Brédas, Seth R. Marder

Research output: Contribution to journal › Article › peer-review

148 Scopus citations

Abstract

(Figure Presented) Benzylphosphonic acids with various fluorine substitutions are designed and synthesized. They are used to modify ITO such that the work function can be tuned over a range of 1.2 eV while keeping the surface energy relatively constant. The experimentally measured work function changes are also compared to and agree well with those estimated from DFT calculations.

Original language	English (US)
Pages (from-to)	4496-4501
Number of pages	6
Journal	Advanced Materials
Volume	21
Issue number	44
DOIs	https://doi.org/10.1002/adma.200900502
State	Published - Nov 26 2009
Externally published	Yes

ASJC Scopus subject areas

General Materials Science
Mechanics of Materials
Mechanical Engineering

Access to Document

10.1002/adma.200900502

Cite this

@article{87db07a4e82943d8a94ecfd2d3406220,

title = "Modification of the surface properties of indium tin oxide with benzylphosphonic acids: A joint experimental and theoretical study",

abstract = "(Figure Presented) Benzylphosphonic acids with various fluorine substitutions are designed and synthesized. They are used to modify ITO such that the work function can be tuned over a range of 1.2 eV while keeping the surface energy relatively constant. The experimentally measured work function changes are also compared to and agree well with those estimated from DFT calculations.",

author = "Hotchkiss, {Peter J.} and Hong Li and Paramonov, {Pavel B.} and Paniagua, {Sergio A.} and Jones, {Simon C.} and Armstrong, {Neal R.} and Br{\'e}das, {Jean Luc} and Marder, {Seth R.}",

year = "2009",

month = nov,

day = "26",

doi = "10.1002/adma.200900502",

language = "English (US)",

volume = "21",

pages = "4496--4501",

journal = "Advanced Materials",

issn = "0935-9648",

publisher = "WILEY-V C H VERLAG GMBH",

number = "44",

}

TY - JOUR

T1 - Modification of the surface properties of indium tin oxide with benzylphosphonic acids

T2 - A joint experimental and theoretical study

AU - Hotchkiss, Peter J.

AU - Li, Hong

AU - Paramonov, Pavel B.

AU - Paniagua, Sergio A.

AU - Jones, Simon C.

AU - Armstrong, Neal R.

AU - Brédas, Jean Luc

AU - Marder, Seth R.

PY - 2009/11/26

Y1 - 2009/11/26

N2 - (Figure Presented) Benzylphosphonic acids with various fluorine substitutions are designed and synthesized. They are used to modify ITO such that the work function can be tuned over a range of 1.2 eV while keeping the surface energy relatively constant. The experimentally measured work function changes are also compared to and agree well with those estimated from DFT calculations.

AB - (Figure Presented) Benzylphosphonic acids with various fluorine substitutions are designed and synthesized. They are used to modify ITO such that the work function can be tuned over a range of 1.2 eV while keeping the surface energy relatively constant. The experimentally measured work function changes are also compared to and agree well with those estimated from DFT calculations.

UR - http://www.scopus.com/inward/record.url?scp=72049100924&partnerID=8YFLogxK

U2 - 10.1002/adma.200900502

DO - 10.1002/adma.200900502

M3 - Article

AN - SCOPUS:72049100924

SN - 0935-9648

VL - 21

SP - 4496

EP - 4501

JO - Advanced Materials

JF - Advanced Materials

IS - 44

ER -

Modification of the surface properties of indium tin oxide with benzylphosphonic acids: A joint experimental and theoretical study

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this