Modification of surfaces and interfaces by non-covalent assembly of hybrid linear-dendritic block copolymers: Poly(benzyl ether) dendrons as anchors for poly(ethylene glycol) chains on cellulose or polyester

Jean M.J. Fréchet; Ivan Gitsov; Thierry Monteil; Sandrine Rochat; Jean François Sassi; Caroll Vergelati; Dong Yu

doi:10.1021/cm981021j

Modification of surfaces and interfaces by non-covalent assembly of hybrid linear-dendritic block copolymers: Poly(benzyl ether) dendrons as anchors for poly(ethylene glycol) chains on cellulose or polyester

Jean M.J. Fréchet^*, Ivan Gitsov, Thierry Monteil, Sandrine Rochat, Jean François Sassi, Caroll Vergelati, Dong Yu

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

60 Scopus citations

Abstract

Solution and interfacial properties of water-soluble hybrid linear-dendritic polyether copolymers are investigated by static and dynamic surface tension measurements and adsorption experiments on polymeric substrates. The results obtained show that the block copolymers are able to form mono- and multimolecular aggregates in water. Contacting a solid polymeric substrate with an aqueous solution of hybrid block copolymer increases the hydrophilicity of the substrate. Adsorption on the hydrophobic surface of poly(ethylene terephthalate) proceeds only through the dendritic blocks of the hybrid macromolecule. For more hydrophilic substrates such as regenerated cellulose, both the poly(ethylene glycol) tail and the poly(benzyl ether) dendrons adsorb on the surface, increasing its hydrophilicity.

Original language	English (US)
Pages (from-to)	1267-1274
Number of pages	8
Journal	Chemistry of Materials
Volume	11
Issue number	5
DOIs	https://doi.org/10.1021/cm981021j
State	Published - 1999
Externally published	Yes

ASJC Scopus subject areas

General Chemistry
General Chemical Engineering
Materials Chemistry

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Fréchet, J. M. J., Gitsov, I., Monteil, T., Rochat, S., Sassi, J. F., Vergelati, C., & Yu, D. (1999). Modification of surfaces and interfaces by non-covalent assembly of hybrid linear-dendritic block copolymers: Poly(benzyl ether) dendrons as anchors for poly(ethylene glycol) chains on cellulose or polyester. Chemistry of Materials, 11(5), 1267-1274. https://doi.org/10.1021/cm981021j

@article{3021de93807148aa9c358916a5e28a11,

title = "Modification of surfaces and interfaces by non-covalent assembly of hybrid linear-dendritic block copolymers: Poly(benzyl ether) dendrons as anchors for poly(ethylene glycol) chains on cellulose or polyester",

abstract = "Solution and interfacial properties of water-soluble hybrid linear-dendritic polyether copolymers are investigated by static and dynamic surface tension measurements and adsorption experiments on polymeric substrates. The results obtained show that the block copolymers are able to form mono- and multimolecular aggregates in water. Contacting a solid polymeric substrate with an aqueous solution of hybrid block copolymer increases the hydrophilicity of the substrate. Adsorption on the hydrophobic surface of poly(ethylene terephthalate) proceeds only through the dendritic blocks of the hybrid macromolecule. For more hydrophilic substrates such as regenerated cellulose, both the poly(ethylene glycol) tail and the poly(benzyl ether) dendrons adsorb on the surface, increasing its hydrophilicity.",

author = "Fr{\'e}chet, {Jean M.J.} and Ivan Gitsov and Thierry Monteil and Sandrine Rochat and Sassi, {Jean Fran{\c c}ois} and Caroll Vergelati and Dong Yu",

year = "1999",

doi = "10.1021/cm981021j",

language = "English (US)",

volume = "11",

pages = "1267--1274",

journal = "Chemistry of Materials",

issn = "0897-4756",

publisher = "AMER CHEMICAL SOC",

number = "5",

}

Fréchet, JMJ, Gitsov, I, Monteil, T, Rochat, S, Sassi, JF, Vergelati, C & Yu, D 1999, 'Modification of surfaces and interfaces by non-covalent assembly of hybrid linear-dendritic block copolymers: Poly(benzyl ether) dendrons as anchors for poly(ethylene glycol) chains on cellulose or polyester', Chemistry of Materials, vol. 11, no. 5, pp. 1267-1274. https://doi.org/10.1021/cm981021j

Modification of surfaces and interfaces by non-covalent assembly of hybrid linear-dendritic block copolymers: Poly(benzyl ether) dendrons as anchors for poly(ethylene glycol) chains on cellulose or polyester. / Fréchet, Jean M.J.; Gitsov, Ivan; Monteil, Thierry et al.
In: Chemistry of Materials, Vol. 11, No. 5, 1999, p. 1267-1274.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Modification of surfaces and interfaces by non-covalent assembly of hybrid linear-dendritic block copolymers

T2 - Poly(benzyl ether) dendrons as anchors for poly(ethylene glycol) chains on cellulose or polyester

AU - Fréchet, Jean M.J.

AU - Gitsov, Ivan

AU - Monteil, Thierry

AU - Rochat, Sandrine

AU - Sassi, Jean François

AU - Vergelati, Caroll

AU - Yu, Dong

PY - 1999

Y1 - 1999

N2 - Solution and interfacial properties of water-soluble hybrid linear-dendritic polyether copolymers are investigated by static and dynamic surface tension measurements and adsorption experiments on polymeric substrates. The results obtained show that the block copolymers are able to form mono- and multimolecular aggregates in water. Contacting a solid polymeric substrate with an aqueous solution of hybrid block copolymer increases the hydrophilicity of the substrate. Adsorption on the hydrophobic surface of poly(ethylene terephthalate) proceeds only through the dendritic blocks of the hybrid macromolecule. For more hydrophilic substrates such as regenerated cellulose, both the poly(ethylene glycol) tail and the poly(benzyl ether) dendrons adsorb on the surface, increasing its hydrophilicity.

AB - Solution and interfacial properties of water-soluble hybrid linear-dendritic polyether copolymers are investigated by static and dynamic surface tension measurements and adsorption experiments on polymeric substrates. The results obtained show that the block copolymers are able to form mono- and multimolecular aggregates in water. Contacting a solid polymeric substrate with an aqueous solution of hybrid block copolymer increases the hydrophilicity of the substrate. Adsorption on the hydrophobic surface of poly(ethylene terephthalate) proceeds only through the dendritic blocks of the hybrid macromolecule. For more hydrophilic substrates such as regenerated cellulose, both the poly(ethylene glycol) tail and the poly(benzyl ether) dendrons adsorb on the surface, increasing its hydrophilicity.

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U2 - 10.1021/cm981021j

DO - 10.1021/cm981021j

M3 - Article

AN - SCOPUS:0000577033

SN - 0897-4756

VL - 11

SP - 1267

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JO - Chemistry of Materials

JF - Chemistry of Materials

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ER -

Modification of surfaces and interfaces by non-covalent assembly of hybrid linear-dendritic block copolymers: Poly(benzyl ether) dendrons as anchors for poly(ethylene glycol) chains on cellulose or polyester

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