Modification of Polyhedral Oligomeric Silsesquioxanes (POSS) Molecules by Ruthenium Catalyzed Cross Metathesis

Justyna Czaban-Jozwiak; Lukasz Wozniak; Artur Ulikowski; Katarzyna Kwiecinska; Adam A. Rajkiewicz; Karol Grela

doi:10.3390/molecules23071722

Modification of Polyhedral Oligomeric Silsesquioxanes (POSS) Molecules by Ruthenium Catalyzed Cross Metathesis

Justyna Czaban-Jozwiak, Lukasz Wozniak, Artur Ulikowski, Katarzyna Kwiecinska, Adam A. Rajkiewicz, Karol Grela

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

The scope of ruthenium (Ru)-catalyzed cross metathesis (CM) of allyl-decorated polyhedral oligomeric silsesquioxanes (POSS) was explored. A variety of different commercial and non-commercial ruthenium complexes were tested to determine that the nitro-activated Ru catalyst is optimal for this transformation. The reported transformation was used to prepare selected hybrid steroid-POSS compounds.

Original language	English (US)
Pages (from-to)	1722
Journal	Molecules
Volume	23
Issue number	7
DOIs	https://doi.org/10.3390/molecules23071722
State	Published - Jul 11 2018
Externally published	Yes

Bibliographical note

KAUST Repository Item: Exported on 2021-07-08
Acknowledgements: The authors would like to thank Erik Abbenhuis and Gijsbert Gerritsen from Hybrid Catalysis BV for their generous donation of the POSS derivatives used in this studies.

ASJC Scopus subject areas

Organic Chemistry

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10.3390/molecules23071722

https://repository.kaust.edu.sa/bitstream/10754/670064/1/molecules-23-01722.pdf

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title = "Modification of Polyhedral Oligomeric Silsesquioxanes (POSS) Molecules by Ruthenium Catalyzed Cross Metathesis",

abstract = "The scope of ruthenium (Ru)-catalyzed cross metathesis (CM) of allyl-decorated polyhedral oligomeric silsesquioxanes (POSS) was explored. A variety of different commercial and non-commercial ruthenium complexes were tested to determine that the nitro-activated Ru catalyst is optimal for this transformation. The reported transformation was used to prepare selected hybrid steroid-POSS compounds.",

author = "Justyna Czaban-Jozwiak and Lukasz Wozniak and Artur Ulikowski and Katarzyna Kwiecinska and Rajkiewicz, {Adam A.} and Karol Grela",

note = "KAUST Repository Item: Exported on 2021-07-08 Acknowledgements: The authors would like to thank Erik Abbenhuis and Gijsbert Gerritsen from Hybrid Catalysis BV for their generous donation of the POSS derivatives used in this studies.",

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AU - Czaban-Jozwiak, Justyna

AU - Wozniak, Lukasz

AU - Ulikowski, Artur

AU - Kwiecinska, Katarzyna

AU - Rajkiewicz, Adam A.

AU - Grela, Karol

N1 - KAUST Repository Item: Exported on 2021-07-08 Acknowledgements: The authors would like to thank Erik Abbenhuis and Gijsbert Gerritsen from Hybrid Catalysis BV for their generous donation of the POSS derivatives used in this studies.

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Y1 - 2018/7/11

N2 - The scope of ruthenium (Ru)-catalyzed cross metathesis (CM) of allyl-decorated polyhedral oligomeric silsesquioxanes (POSS) was explored. A variety of different commercial and non-commercial ruthenium complexes were tested to determine that the nitro-activated Ru catalyst is optimal for this transformation. The reported transformation was used to prepare selected hybrid steroid-POSS compounds.

AB - The scope of ruthenium (Ru)-catalyzed cross metathesis (CM) of allyl-decorated polyhedral oligomeric silsesquioxanes (POSS) was explored. A variety of different commercial and non-commercial ruthenium complexes were tested to determine that the nitro-activated Ru catalyst is optimal for this transformation. The reported transformation was used to prepare selected hybrid steroid-POSS compounds.

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JF - Molecules

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ER -

Modification of Polyhedral Oligomeric Silsesquioxanes (POSS) Molecules by Ruthenium Catalyzed Cross Metathesis

Abstract

Bibliographical note

ASJC Scopus subject areas

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