Miktoarm block copolymer formation via ionic interactions

S. Pispas, G. Floudas*, T. Pakula, G. Lieser, S. Sakellariou, N. Hadjichristidis

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

47 Scopus citations


Blends of functionalized polystyrenes (3NPS) having three dimethylamino groups {N(CH3)2} at one end, with sulfonic acid end-capped polyisoprenes (HO3SPI) were prepared in a ratio of N(CH3)2/SO3H = 1. The morphology of these blends was studied by small-angle X-ray scattering and transmission electron microscopy and the associated dynamics by rheology. The results of the microdomain investigation, as well as of the associated dynamics, provide unambiguous evidence for controlled miktoarm star block copolymer formation via ionic interactions.

Original languageEnglish (US)
Pages (from-to)759-763
Number of pages5
Issue number3
StatePublished - Feb 11 2003
Externally publishedYes

ASJC Scopus subject areas

  • Materials Chemistry
  • Polymers and Plastics
  • Inorganic Chemistry
  • Organic Chemistry


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