Mid-infrared dual frequency comb spectroscopy for combustion analysis from 2.8 to 5 μm

Amanda S. Makowiecki; Daniel I. Herman; Nazanin Hoghooghi; Elizabeth F. Strong; Ryan K. Cole; Gabe Ycas; Fabrizio R. Giorgetta; Caelan B. Lapointe; Jeffrey F. Glusman; John W. Daily; Peter E. Hamlington; Nathan R. Newbury; Ian R. Coddington; Gregory B. Rieker

doi:10.1016/j.proci.2020.06.195

Mid-infrared dual frequency comb spectroscopy for combustion analysis from 2.8 to 5 μm

Amanda S. Makowiecki, Daniel I. Herman, Nazanin Hoghooghi, Elizabeth F. Strong, Ryan K. Cole, Gabe Ycas, Fabrizio R. Giorgetta, Caelan B. Lapointe, Jeffrey F. Glusman, John W. Daily, Peter E. Hamlington, Nathan R. Newbury, Ian R. Coddington, Gregory B. Rieker

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

42 Scopus citations

Abstract

We demonstrate the application of mode-locked mid-infrared dual frequency comb spectroscopy for combustion analysis. With two settings of the same dual-comb system, the measurement spans 1500 cm-1 from 2.8 to 5 μm with 0.0067 cm-1 (200 MHz) point spacing, or almost a quarter-million discrete comb modes. Using this broadband spectrometer, we quantify the pyrolysis and smoldering combustion of wood samples. Specifically, we measure 20-second time-resolved mole fractions of CH4, H2O, two isotopologues of CO2 (12C16O2, 13C16O2), two isotopologues of CO (12C16O, 13C16O), ethane, formaldehyde, methanol, formic acid, as well as gas temperature directly above radiatively heated wood samples. The combination of the fine spectral resolution and the broad bandwidth of the dual-comb spectrometer allows for precise separation of absorption signatures of individual molecules from the congested spectra.

Original language	English (US)
Title of host publication	Proceedings of the Combustion Institute
Publisher	Elsevier BV
Pages	1627-1635
Number of pages	9
DOIs	https://doi.org/10.1016/j.proci.2020.06.195
State	Published - Apr 10 2021
Externally published	Yes

Bibliographical note

KAUST Repository Item: Exported on 2022-06-30
Acknowledgements: We thank Dr. Aamir Farooq of King Abdullah University of Science and Technology and Dr. Timothy Johnson of Pacific Northwest National Laboratory for providing absorption cross-section reference sets. This work was supported by the Strategic Environmental Research and Development Program (W912HQ-16-C-0026), the National Science Foundation (CBET 1454496), the Defense Advanced Research Projects Agency (W31P4Q-15-1-0011), and NIST.
This publication acknowledges KAUST support, but has no KAUST affiliated authors.

ASJC Scopus subject areas

General Chemical Engineering
Mechanical Engineering
Physical and Theoretical Chemistry

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10.1016/j.proci.2020.06.195

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Makowiecki, A. S., Herman, D. I., Hoghooghi, N., Strong, E. F., Cole, R. K., Ycas, G., Giorgetta, F. R., Lapointe, C. B., Glusman, J. F., Daily, J. W., Hamlington, P. E., Newbury, N. R., Coddington, I. R., & Rieker, G. B. (2021). Mid-infrared dual frequency comb spectroscopy for combustion analysis from 2.8 to 5 μm. In Proceedings of the Combustion Institute (pp. 1627-1635). Elsevier BV. https://doi.org/10.1016/j.proci.2020.06.195

@inproceedings{11feccf449dc47f090c1cdea3b15dba9,

title = "Mid-infrared dual frequency comb spectroscopy for combustion analysis from 2.8 to 5 μm",

abstract = "We demonstrate the application of mode-locked mid-infrared dual frequency comb spectroscopy for combustion analysis. With two settings of the same dual-comb system, the measurement spans 1500 cm-1 from 2.8 to 5 μm with 0.0067 cm-1 (200 MHz) point spacing, or almost a quarter-million discrete comb modes. Using this broadband spectrometer, we quantify the pyrolysis and smoldering combustion of wood samples. Specifically, we measure 20-second time-resolved mole fractions of CH4, H2O, two isotopologues of CO2 (12C16O2, 13C16O2), two isotopologues of CO (12C16O, 13C16O), ethane, formaldehyde, methanol, formic acid, as well as gas temperature directly above radiatively heated wood samples. The combination of the fine spectral resolution and the broad bandwidth of the dual-comb spectrometer allows for precise separation of absorption signatures of individual molecules from the congested spectra.",

author = "Makowiecki, {Amanda S.} and Herman, {Daniel I.} and Nazanin Hoghooghi and Strong, {Elizabeth F.} and Cole, {Ryan K.} and Gabe Ycas and Giorgetta, {Fabrizio R.} and Lapointe, {Caelan B.} and Glusman, {Jeffrey F.} and Daily, {John W.} and Hamlington, {Peter E.} and Newbury, {Nathan R.} and Coddington, {Ian R.} and Rieker, {Gregory B.}",

note = "KAUST Repository Item: Exported on 2022-06-30 Acknowledgements: We thank Dr. Aamir Farooq of King Abdullah University of Science and Technology and Dr. Timothy Johnson of Pacific Northwest National Laboratory for providing absorption cross-section reference sets. This work was supported by the Strategic Environmental Research and Development Program (W912HQ-16-C-0026), the National Science Foundation (CBET 1454496), the Defense Advanced Research Projects Agency (W31P4Q-15-1-0011), and NIST. This publication acknowledges KAUST support, but has no KAUST affiliated authors.",

year = "2021",

month = apr,

day = "10",

doi = "10.1016/j.proci.2020.06.195",

language = "English (US)",

pages = "1627--1635",

booktitle = "Proceedings of the Combustion Institute",

publisher = "Elsevier BV",

}

Makowiecki, AS, Herman, DI, Hoghooghi, N, Strong, EF, Cole, RK, Ycas, G, Giorgetta, FR, Lapointe, CB, Glusman, JF, Daily, JW, Hamlington, PE, Newbury, NR, Coddington, IR & Rieker, GB 2021, Mid-infrared dual frequency comb spectroscopy for combustion analysis from 2.8 to 5 μm. in Proceedings of the Combustion Institute. Elsevier BV, pp. 1627-1635. https://doi.org/10.1016/j.proci.2020.06.195

TY - GEN

T1 - Mid-infrared dual frequency comb spectroscopy for combustion analysis from 2.8 to 5 μm

AU - Makowiecki, Amanda S.

AU - Herman, Daniel I.

AU - Hoghooghi, Nazanin

AU - Strong, Elizabeth F.

AU - Cole, Ryan K.

AU - Ycas, Gabe

AU - Giorgetta, Fabrizio R.

AU - Lapointe, Caelan B.

AU - Glusman, Jeffrey F.

AU - Daily, John W.

AU - Hamlington, Peter E.

AU - Newbury, Nathan R.

AU - Coddington, Ian R.

AU - Rieker, Gregory B.

N1 - KAUST Repository Item: Exported on 2022-06-30 Acknowledgements: We thank Dr. Aamir Farooq of King Abdullah University of Science and Technology and Dr. Timothy Johnson of Pacific Northwest National Laboratory for providing absorption cross-section reference sets. This work was supported by the Strategic Environmental Research and Development Program (W912HQ-16-C-0026), the National Science Foundation (CBET 1454496), the Defense Advanced Research Projects Agency (W31P4Q-15-1-0011), and NIST. This publication acknowledges KAUST support, but has no KAUST affiliated authors.

PY - 2021/4/10

Y1 - 2021/4/10

N2 - We demonstrate the application of mode-locked mid-infrared dual frequency comb spectroscopy for combustion analysis. With two settings of the same dual-comb system, the measurement spans 1500 cm-1 from 2.8 to 5 μm with 0.0067 cm-1 (200 MHz) point spacing, or almost a quarter-million discrete comb modes. Using this broadband spectrometer, we quantify the pyrolysis and smoldering combustion of wood samples. Specifically, we measure 20-second time-resolved mole fractions of CH4, H2O, two isotopologues of CO2 (12C16O2, 13C16O2), two isotopologues of CO (12C16O, 13C16O), ethane, formaldehyde, methanol, formic acid, as well as gas temperature directly above radiatively heated wood samples. The combination of the fine spectral resolution and the broad bandwidth of the dual-comb spectrometer allows for precise separation of absorption signatures of individual molecules from the congested spectra.

AB - We demonstrate the application of mode-locked mid-infrared dual frequency comb spectroscopy for combustion analysis. With two settings of the same dual-comb system, the measurement spans 1500 cm-1 from 2.8 to 5 μm with 0.0067 cm-1 (200 MHz) point spacing, or almost a quarter-million discrete comb modes. Using this broadband spectrometer, we quantify the pyrolysis and smoldering combustion of wood samples. Specifically, we measure 20-second time-resolved mole fractions of CH4, H2O, two isotopologues of CO2 (12C16O2, 13C16O2), two isotopologues of CO (12C16O, 13C16O), ethane, formaldehyde, methanol, formic acid, as well as gas temperature directly above radiatively heated wood samples. The combination of the fine spectral resolution and the broad bandwidth of the dual-comb spectrometer allows for precise separation of absorption signatures of individual molecules from the congested spectra.

UR - http://hdl.handle.net/10754/679507

UR - https://linkinghub.elsevier.com/retrieve/pii/S1540748920302868

UR - http://www.scopus.com/inward/record.url?scp=85091922392&partnerID=8YFLogxK

U2 - 10.1016/j.proci.2020.06.195

DO - 10.1016/j.proci.2020.06.195

M3 - Conference contribution

SP - 1627

EP - 1635

BT - Proceedings of the Combustion Institute

PB - Elsevier BV

ER -

Mid-infrared dual frequency comb spectroscopy for combustion analysis from 2.8 to 5 μm

Abstract

Bibliographical note

ASJC Scopus subject areas

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