Microporous heptazine functionalized (3,24)-connected rht-metal-organic framework: Synthesis, structure, and gas sorption analysis

Ryan Luebke; Lukasz Jan Weselinski; Youssef Belmabkhout; Zhijie Chen; Łukasz Wojtas; Mohamed Eddaoudi

doi:10.1021/cg401802s

Microporous heptazine functionalized (3,24)-connected rht-metal-organic framework: Synthesis, structure, and gas sorption analysis

Ryan Luebke, Lukasz Jan Weselinski, Youssef Belmabkhout, Zhijie Chen, Łukasz Wojtas, Mohamed Eddaoudi

Research output: Contribution to journal › Article › peer-review

72 Scopus citations

Abstract

Here we synthesized the highly porous rht-MOF-9 as the first example of an rht-MOF having a polycyclic central core. This material was synthesized from a predesigned polyheterocyclic nitrogen-rich hexacarboxylate (tri-isophthalate) ligand, which serves as the 3-connected, trigonal molecular building block (MBB). When reacted under the proper conditions, this ligand, having three coplanar isophthalic acid moieties, codes for the in situ formation of the targeted 24-connected copper-based supermolecular building block (SBB) having rhombicuboctahedral geometry. This combination of a 24-connected building block linked through 3-connected nodes results in a novel material with the singular rht topology. The rht-MOF-9 compound exhibits promising H2 and CO2 adsorption properties in comparison to previously reported rht-MOFs. © 2014 American Chemical Society.

Original language	English (US)
Pages (from-to)	414-418
Number of pages	5
Journal	Crystal Growth & Design
Volume	14
Issue number	2
DOIs	https://doi.org/10.1021/cg401802s
State	Published - Jan 17 2014

Bibliographical note

KAUST Repository Item: Exported on 2020-10-01
Acknowledgements: Authors gratefully acknowledge KAUST for funding.

ASJC Scopus subject areas

General Materials Science
General Chemistry
Condensed Matter Physics

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10.1021/cg401802s

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@article{b2e814cf395d4cdfb7bc06c47d1db890,

title = "Microporous heptazine functionalized (3,24)-connected rht-metal-organic framework: Synthesis, structure, and gas sorption analysis",

abstract = "Here we synthesized the highly porous rht-MOF-9 as the first example of an rht-MOF having a polycyclic central core. This material was synthesized from a predesigned polyheterocyclic nitrogen-rich hexacarboxylate (tri-isophthalate) ligand, which serves as the 3-connected, trigonal molecular building block (MBB). When reacted under the proper conditions, this ligand, having three coplanar isophthalic acid moieties, codes for the in situ formation of the targeted 24-connected copper-based supermolecular building block (SBB) having rhombicuboctahedral geometry. This combination of a 24-connected building block linked through 3-connected nodes results in a novel material with the singular rht topology. The rht-MOF-9 compound exhibits promising H2 and CO2 adsorption properties in comparison to previously reported rht-MOFs. {\textcopyright} 2014 American Chemical Society.",

author = "Ryan Luebke and Weselinski, {Lukasz Jan} and Youssef Belmabkhout and Zhijie Chen and {\L}ukasz Wojtas and Mohamed Eddaoudi",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: Authors gratefully acknowledge KAUST for funding.",

year = "2014",

month = jan,

day = "17",

doi = "10.1021/cg401802s",

language = "English (US)",

volume = "14",

pages = "414--418",

journal = "Crystal Growth & Design",

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AU - Luebke, Ryan

AU - Weselinski, Lukasz Jan

AU - Belmabkhout, Youssef

AU - Chen, Zhijie

AU - Wojtas, Łukasz

AU - Eddaoudi, Mohamed

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: Authors gratefully acknowledge KAUST for funding.

PY - 2014/1/17

Y1 - 2014/1/17

N2 - Here we synthesized the highly porous rht-MOF-9 as the first example of an rht-MOF having a polycyclic central core. This material was synthesized from a predesigned polyheterocyclic nitrogen-rich hexacarboxylate (tri-isophthalate) ligand, which serves as the 3-connected, trigonal molecular building block (MBB). When reacted under the proper conditions, this ligand, having three coplanar isophthalic acid moieties, codes for the in situ formation of the targeted 24-connected copper-based supermolecular building block (SBB) having rhombicuboctahedral geometry. This combination of a 24-connected building block linked through 3-connected nodes results in a novel material with the singular rht topology. The rht-MOF-9 compound exhibits promising H2 and CO2 adsorption properties in comparison to previously reported rht-MOFs. © 2014 American Chemical Society.

AB - Here we synthesized the highly porous rht-MOF-9 as the first example of an rht-MOF having a polycyclic central core. This material was synthesized from a predesigned polyheterocyclic nitrogen-rich hexacarboxylate (tri-isophthalate) ligand, which serves as the 3-connected, trigonal molecular building block (MBB). When reacted under the proper conditions, this ligand, having three coplanar isophthalic acid moieties, codes for the in situ formation of the targeted 24-connected copper-based supermolecular building block (SBB) having rhombicuboctahedral geometry. This combination of a 24-connected building block linked through 3-connected nodes results in a novel material with the singular rht topology. The rht-MOF-9 compound exhibits promising H2 and CO2 adsorption properties in comparison to previously reported rht-MOFs. © 2014 American Chemical Society.

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U2 - 10.1021/cg401802s

DO - 10.1021/cg401802s

M3 - Article

SN - 1528-7483

VL - 14

SP - 414

EP - 418

JO - Crystal Growth & Design

JF - Crystal Growth & Design

IS - 2

ER -

Microporous heptazine functionalized (3,24)-connected rht-metal-organic framework: Synthesis, structure, and gas sorption analysis

Abstract

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CCDC 974613: Experimental Crystal Structure Determination : catena-[bis(mu-5,5',5''-(1,3,4,6,7,9,9b-heptaazaphenalene-2,5,8-triyltriimino)triisophthalato)-tris(dimethyl sulfoxide)-triaqua-hexa-copper dimethyl sulfoxide solvate hydrate]

Cite this

Microporous heptazine functionalized (3,24)-connected rht-metal-organic framework: Synthesis, structure, and gas sorption analysis

Abstract

Bibliographical note

ASJC Scopus subject areas

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Datasets

CCDC 974613: Experimental Crystal Structure Determination : catena-[bis(mu-5,5',5''-(1,3,4,6,7,9,9b-heptaazaphenalene-2,5,8-triyltriimino)triisophthalato)-tris(dimethyl sulfoxide)-triaqua-hexa-copper dimethyl sulfoxide solvate hydrate]

Cite this