MgFePO4F as a feasible cathode material for magnesium batteries

Zhen Dong Huang; Titus Masese; Yuki Orikasa; Takuya Mori; Taketoshi Minato; Cedric Tassel; Yoji Kobayashi; Hiroshi Kageyama; Yoshiharu Uchimoto

doi:10.1039/c4ta01779j

MgFePO4F as a feasible cathode material for magnesium batteries

Zhen Dong Huang, Titus Masese, Yuki Orikasa, Takuya Mori, Taketoshi Minato, Cedric Tassel, Yoji Kobayashi, Hiroshi Kageyama, Yoshiharu Uchimoto

Research output: Contribution to journal › Article › peer-review

76 Scopus citations

Abstract

A stoichiometric MgFePO4F (MFPF) is synthesised by using a solid-state carbothermal method. Its monoclinic framework, possessing an entire cationic mixing of Mg2+ and Fe2+, is validated via both crystal structure analysis and simulation. Interestingly, MFPF exhibits a relatively high potential (∼2.6 V vs. Mg/Mg2+) and good cyclic stability with an encouraging capacity (∼53 mA h g-1), bringing MFPF to the fore as a promising cathode material for magnesium batteries. This journal is © the Partner Organisations 2014.

Original language	English (US)
Pages (from-to)	11578-11582
Number of pages	5
Journal	Journal of Materials Chemistry A
Volume	2
Issue number	30
DOIs	https://doi.org/10.1039/c4ta01779j
State	Published - Aug 14 2014
Externally published	Yes

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Generated from Scopus record by KAUST IRTS on 2022-09-13

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title = "MgFePO4F as a feasible cathode material for magnesium batteries",

abstract = "A stoichiometric MgFePO4F (MFPF) is synthesised by using a solid-state carbothermal method. Its monoclinic framework, possessing an entire cationic mixing of Mg2+ and Fe2+, is validated via both crystal structure analysis and simulation. Interestingly, MFPF exhibits a relatively high potential (∼2.6 V vs. Mg/Mg2+) and good cyclic stability with an encouraging capacity (∼53 mA h g-1), bringing MFPF to the fore as a promising cathode material for magnesium batteries. This journal is {\textcopyright} the Partner Organisations 2014.",

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doi = "10.1039/c4ta01779j",

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T1 - MgFePO4F as a feasible cathode material for magnesium batteries

AU - Huang, Zhen Dong

AU - Masese, Titus

AU - Orikasa, Yuki

AU - Mori, Takuya

AU - Minato, Taketoshi

AU - Tassel, Cedric

AU - Kobayashi, Yoji

AU - Kageyama, Hiroshi

AU - Uchimoto, Yoshiharu

N1 - Generated from Scopus record by KAUST IRTS on 2022-09-13

PY - 2014/8/14

Y1 - 2014/8/14

N2 - A stoichiometric MgFePO4F (MFPF) is synthesised by using a solid-state carbothermal method. Its monoclinic framework, possessing an entire cationic mixing of Mg2+ and Fe2+, is validated via both crystal structure analysis and simulation. Interestingly, MFPF exhibits a relatively high potential (∼2.6 V vs. Mg/Mg2+) and good cyclic stability with an encouraging capacity (∼53 mA h g-1), bringing MFPF to the fore as a promising cathode material for magnesium batteries. This journal is © the Partner Organisations 2014.

AB - A stoichiometric MgFePO4F (MFPF) is synthesised by using a solid-state carbothermal method. Its monoclinic framework, possessing an entire cationic mixing of Mg2+ and Fe2+, is validated via both crystal structure analysis and simulation. Interestingly, MFPF exhibits a relatively high potential (∼2.6 V vs. Mg/Mg2+) and good cyclic stability with an encouraging capacity (∼53 mA h g-1), bringing MFPF to the fore as a promising cathode material for magnesium batteries. This journal is © the Partner Organisations 2014.

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DO - 10.1039/c4ta01779j

M3 - Article

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VL - 2

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EP - 11582

JO - Journal of Materials Chemistry A

JF - Journal of Materials Chemistry A

IS - 30

ER -

MgFePO4F as a feasible cathode material for magnesium batteries

Abstract

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