Methylcyclohexane pyrolysis and oxidation in a jet-stirred reactor

Tony Bissoonauth; Zhandong Wang; Samah Mohamed; Jui-Yang Wang; Bingjie Chen; Anne Rodriguez; Ophélie Frottier; Xiaoyuan Zhang; Yan Zhang; Chuangchuang Cao; Juizhong Yang; Olivier Herbinet; Frédérique Battin-Leclerc; Mani Sarathy

doi:10.1016/j.proci.2018.05.086

Methylcyclohexane pyrolysis and oxidation in a jet-stirred reactor

Tony Bissoonauth, Zhandong Wang, Samah Mohamed, Jui-Yang Wang, Bingjie Chen, Anne Rodriguez, Ophélie Frottier, Xiaoyuan Zhang, Yan Zhang, Chuangchuang Cao, Juizhong Yang, Olivier Herbinet, Frédérique Battin-Leclerc, Mani Sarathy

Research output: Contribution to journal › Article › peer-review

42 Scopus citations

Abstract

Alkylated cycloalkanes are an important chemical class in conventional fuels. Methylcyclohexane (MCH) is a simple alkylated cycloalkane that is a potential candidate to represent the naphthenic content in transportation fuel surrogates. Detailed experimental speciation data for MCH gas-phase oxidation and pyrolysis is still lacking in the literature. This work investigates the high-temperature pyrolysis and low-temperature oxidation of MCH in a jet-stirred reactor. Under low-temperature conditions, highly oxygenated intermediate species indicative of

Original language	English (US)
Pages (from-to)	409-417
Number of pages	9
Journal	Proceedings of the Combustion Institute
Volume	37
Issue number	1
DOIs	https://doi.org/10.1016/j.proci.2018.05.086
State	Published - Jul 27 2018

Bibliographical note

KAUST Repository Item: Exported on 2020-10-01
Acknowledged KAUST grant number(s): OSR-2016-CRG5-3022
Acknowledgements: This work was supported by: King Abdullah University of Science and Technology (KAUST), Office of Sponsored Research (OSR) under Award No. OSR-2016-CRG5-3022, and Saudi Aramco under the FUELCOM program. European Commission (“Clean ICE” ERC Advanced Research Grant, 2008–2013) is thanked for supporting Nancy experiments.

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https://repository.kaust.edu.sa/bitstream/10754/631349/1/MCH%20OXIDATION-R2.pdf

Cite this

@article{5431328269fe4d04b021315f0924b789,

title = "Methylcyclohexane pyrolysis and oxidation in a jet-stirred reactor",

abstract = "Alkylated cycloalkanes are an important chemical class in conventional fuels. Methylcyclohexane (MCH) is a simple alkylated cycloalkane that is a potential candidate to represent the naphthenic content in transportation fuel surrogates. Detailed experimental speciation data for MCH gas-phase oxidation and pyrolysis is still lacking in the literature. This work investigates the high-temperature pyrolysis and low-temperature oxidation of MCH in a jet-stirred reactor. Under low-temperature conditions, highly oxygenated intermediate species indicative of",

author = "Tony Bissoonauth and Zhandong Wang and Samah Mohamed and Jui-Yang Wang and Bingjie Chen and Anne Rodriguez and Oph{\'e}lie Frottier and Xiaoyuan Zhang and Yan Zhang and Chuangchuang Cao and Juizhong Yang and Olivier Herbinet and Fr{\'e}d{\'e}rique Battin-Leclerc and Mani Sarathy",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledged KAUST grant number(s): OSR-2016-CRG5-3022 Acknowledgements: This work was supported by: King Abdullah University of Science and Technology (KAUST), Office of Sponsored Research (OSR) under Award No. OSR-2016-CRG5-3022, and Saudi Aramco under the FUELCOM program. European Commission (“Clean ICE” ERC Advanced Research Grant, 2008–2013) is thanked for supporting Nancy experiments.",

year = "2018",

month = jul,

day = "27",

doi = "10.1016/j.proci.2018.05.086",

language = "English (US)",

volume = "37",

pages = "409--417",

journal = "Proceedings of the Combustion Institute",

issn = "1540-7489",

publisher = "Elsevier",

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T1 - Methylcyclohexane pyrolysis and oxidation in a jet-stirred reactor

AU - Bissoonauth, Tony

AU - Wang, Zhandong

AU - Mohamed, Samah

AU - Wang, Jui-Yang

AU - Chen, Bingjie

AU - Rodriguez, Anne

AU - Frottier, Ophélie

AU - Zhang, Xiaoyuan

AU - Zhang, Yan

AU - Cao, Chuangchuang

AU - Yang, Juizhong

AU - Herbinet, Olivier

AU - Battin-Leclerc, Frédérique

AU - Sarathy, Mani

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledged KAUST grant number(s): OSR-2016-CRG5-3022 Acknowledgements: This work was supported by: King Abdullah University of Science and Technology (KAUST), Office of Sponsored Research (OSR) under Award No. OSR-2016-CRG5-3022, and Saudi Aramco under the FUELCOM program. European Commission (“Clean ICE” ERC Advanced Research Grant, 2008–2013) is thanked for supporting Nancy experiments.

PY - 2018/7/27

Y1 - 2018/7/27

N2 - Alkylated cycloalkanes are an important chemical class in conventional fuels. Methylcyclohexane (MCH) is a simple alkylated cycloalkane that is a potential candidate to represent the naphthenic content in transportation fuel surrogates. Detailed experimental speciation data for MCH gas-phase oxidation and pyrolysis is still lacking in the literature. This work investigates the high-temperature pyrolysis and low-temperature oxidation of MCH in a jet-stirred reactor. Under low-temperature conditions, highly oxygenated intermediate species indicative of

AB - Alkylated cycloalkanes are an important chemical class in conventional fuels. Methylcyclohexane (MCH) is a simple alkylated cycloalkane that is a potential candidate to represent the naphthenic content in transportation fuel surrogates. Detailed experimental speciation data for MCH gas-phase oxidation and pyrolysis is still lacking in the literature. This work investigates the high-temperature pyrolysis and low-temperature oxidation of MCH in a jet-stirred reactor. Under low-temperature conditions, highly oxygenated intermediate species indicative of

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UR - https://www.sciencedirect.com/science/article/pii/S1540748918300877

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M3 - Article

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VL - 37

SP - 409

EP - 417

JO - Proceedings of the Combustion Institute

JF - Proceedings of the Combustion Institute

IS - 1

ER -

Methylcyclohexane pyrolysis and oxidation in a jet-stirred reactor

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